CRM52554
Spiroxamine
certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
Sinônimo(s):
N-Ethyl-N-propyl-8-tert-butyl-1,4-dioxaspiro[4.5]dec-2-ylmethylamine
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About This Item
Fórmula empírica (Notação de Hill):
C18H35NO2
Número CAS:
Peso molecular:
297.48
Número MDL:
Código UNSPSC:
41116107
NACRES:
NA.24
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grau
certified reference material
TraceCERT®
Nível de qualidade
linha de produto
TraceCERT®
prazo de validade
limited shelf life, expiry date on the label
fabricante/nome comercial
Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
Formato
neat
temperatura de armazenamento
2-8°C
cadeia de caracteres SMILES
CCCN(CC)CC1COC2(CCC(CC2)C(C)(C)C)O1
InChI
1S/C18H35NO2/c1-6-12-19(7-2)13-16-14-20-18(21-16)10-8-15(9-11-18)17(3,4)5/h15-16H,6-14H2,1-5H3
chave InChI
PUYXTUJWRLOUCW-UHFFFAOYSA-N
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Descrição geral
This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.comSpiroxamine is a systemic fungicide that belongs to the class of synthetic amines or morpholines. It targets the ∆14-reductase enzyme and inhibits sterol biosynthesis. It is used against powdery mildew, rust, and spot fungi on cereals and grapes for its protective, curative, and eradicative activities.
As per Regulation (EC) No. 1107/2009, repealing directive 91/414/EEC, spiroxamine is approved for use in the European Union (EU). A maximum residue limit (MRL) of 0.01 mg/kg and 0.05 mg/kg is applicable for the presence of spiroxamine in fresh/frozen fruits and tree nuts respectively, in accordance with Regulation (EC) No. 2016/452. Spiroxamine is to be monitored in the Multiannual Control Programme for Pesticides Residues (MACP), run within the EU and EFTA in/on products of plant origin.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.comSpiroxamine is a systemic fungicide that belongs to the class of synthetic amines or morpholines. It targets the ∆14-reductase enzyme and inhibits sterol biosynthesis. It is used against powdery mildew, rust, and spot fungi on cereals and grapes for its protective, curative, and eradicative activities.
As per Regulation (EC) No. 1107/2009, repealing directive 91/414/EEC, spiroxamine is approved for use in the European Union (EU). A maximum residue limit (MRL) of 0.01 mg/kg and 0.05 mg/kg is applicable for the presence of spiroxamine in fresh/frozen fruits and tree nuts respectively, in accordance with Regulation (EC) No. 2016/452. Spiroxamine is to be monitored in the Multiannual Control Programme for Pesticides Residues (MACP), run within the EU and EFTA in/on products of plant origin.
Aplicação
The certified reference material (CRM) is intended to be used as a calibrant for chromatography and other analytical techniques.
The spiroxamine CRM may also find the following uses:
The spiroxamine CRM may also find the following uses:
- Development of an enantioselective method to determine three fungicide residues in grapevine, sugar beet, and wheat samples by gas chromatography-tandem mass spectrometry (GC-MS/MS)
- Quantification of 19 neonicotinoids and fungicides from pollen and individual bumblebee samples using modified QuEChERS extraction with ultra-high performance liquid chromatography-tandem mass spectrometry (UHPLC-MS/MS)
- Evaluation of a gas chromatographic method with electron capture and nitrogen phosphorus detection (GC/ECD/NPD) for the analysis of 46 pesticides in fresh peppermint samples
- Multi-residue determination of 25 pesticide residues in red wine by gas chromatography-mass spectrometry(GC-MS)
- QuEChERS extraction and liquid chromatography-tandem mass spectrometry based determination of 42 pesticides in six marijuana samples
- Investigation of three different sample preparation methods to select the most suitable one for the analysis of 98 pesticides in globe artichoke leaves and fruit samples by LC-MS and GC-MS
Informações legais
TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany
Palavra indicadora
Warning
Frases de perigo
Declarações de precaução
Classificações de perigo
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Repr. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 2
Órgãos-alvo
Eyes
Código de classe de armazenamento
10 - Combustible liquids
Classe de risco de água (WGK)
WGK 3
Ponto de fulgor (°F)
296.6 °F
Ponto de fulgor (°C)
147 °C
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Certificados de análise (COA)
Lot/Batch Number
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Arthur David et al.
Analytical and bioanalytical chemistry, 407(26), 8151-8162 (2015-09-04)
To accurately estimate exposure of bees to pesticides, analytical methods are needed to enable quantification of nanogram/gram (ng/g) levels of contaminants in small samples of pollen or the individual insects. A modified QuEChERS extraction method coupled with ultra-high-performance liquid chromatography
Ignaz J Buerge et al.
Journal of agricultural and food chemistry, 64(26), 5301-5309 (2016-06-02)
Metabolism of chiral pesticides in crops is typically studied using achiral analytical methods and, consequently, the stereoisomer composition of residues is unknown. In this study, we developed an enantioselective GC-MS/MS method to quantify residues of the fungicides fenpropidin, fenpropimorph, and
Andrea Kunova et al.
Microorganisms, 9(7), 1541-1541 (2021-08-08)
Grapevine powdery mildew is a principal fungal disease of grapevine worldwide. Even though it usually does not cause plant death directly, heavy infections can lead to extensive yield losses, and even low levels of the disease can negatively affect the
Ignacio Machado et al.
Food chemistry, 227, 227-236 (2017-03-10)
Aiming to select the most suitable sample preparation for the multiresidue analysis of pesticides in globe artichoke (Cynara cardunculus L.), a modified QuEChERS, a matrix solid phase dispersion and a dispersive ethyl acetate extraction were compared. Trueness and precision were
Maja Pelajić et al.
Food chemistry, 200, 98-106 (2016-02-03)
A new multiresidue method was developed for determination of 25 pesticide residues in red wine by gas chromatography coupled to mass spectrometry with a single run of 23.63 min. Samples were extracted from wine with solid phase extraction using Oasis
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