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Sigma-Aldrich

Cobalt(II) nitrate hexahydrate

reagent grade, 98%

Sinônimo(s):

Cobaltous nitrate, Cobaltous nitrate hexahydrate, Nitric acid, cobalt(II) salt

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About This Item

Fórmula linear:
Co(NO3)2 · 6H2O
Número CAS:
10026-22-9
Peso molecular:
291.03
Número MDL:
MFCD00149647
Código UNSPSC:
12352302
ID de substância PubChem:
329752369
NACRES:
NA.55

grau

reagent grade

Nível de qualidade

100

Ensaio

98%

forma

flakes
powder, crystals or chunks

adequação da reação

reagent type: catalyst
core: cobalt

pH

4 (20 °C, 100 g/L)

pf

55 °C (lit.)

cadeia de caracteres SMILES

O.O.O.O.O.O.[Co++].[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/Co.2NO3.6H2O/c;2*2-1(3)4;;;;;;/h;;;6*1H2/q+2;2*-1;;;;;;

chave InChI

QGUAJWGNOXCYJF-UHFFFAOYSA-N

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Descrição geral

Cobalt (II) nitrate hexahydrate is a simple, inexpensive and readily available cobalt precursor to develop cobalt-based catalyst for specific organic reactions.

Aplicação

Cobalt (II) nitrate hexahydrate is used as a catalyst:
  • In the synthesis of 5-carboxanilide-dihydropyrimidinone derivatives from acetoacetanilide, aldehyde, and urea/thiourea by condensation reaction.
  • In the multi-component synthesis of 2-amino-3- cyanopyridine and pyranopyrazole derivatives.
  • Cobalt (II) nitrate hexahydrate can also be used:,In the preparation of nano-Co3O4 by direct thermal decomposition, that are used in electrochemical water splitting and electrochemical sensors.

Palavra indicadora

Danger

Classificações de perigo

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B Inhalation - Eye Dam. 1 - Muta. 2 - Ox. Sol. 2 - Repr. 1B - Resp. Sens. 1 - Skin Sens. 1 - STOT RE 2 Inhalation

Órgãos-alvo

Lungs

Código de classe de armazenamento

5.1B - Oxidizing hazardous materials

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable

Certificados de análise (COA)

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Some Phosphine Oxide and Arsine Oxide Complexes of Cobalt (II) Nitrate.
Cotton FA, et al.
Inorganic Chemistry, 2(6), 1162-1165 (1963)
Horacio López-Sandoval et al.
Journal of inorganic biochemistry, 102(5-6), 1267-1276 (2008-02-29)
In this work we present the synthesis, structural and spectroscopic characterisation of a series of cobalt(II) and zinc(II) coordination compounds with benzimidazole (bz) and its 2-benzimidazole derivatives: 2-aminobenzimidazole (2ab), albendazole (abz) and tris(2-benzimidazolylmethyl)amine (ntb). The compounds were evaluated for their
Thermal decomposition of cobalt nitrato compounds: Preparation of anhydrous cobalt (II) nitrate and its characterisation by Infrared and Raman spectra.
Ehrhardt C, et al.
Thermochimica Acta, 432(1), 36-40 (2005)
William Buchmann et al.
Journal of mass spectrometry : JMS, 42(4), 517-526 (2007-02-27)
The electronebulization of a cobalt(II)/cysteine(Cys) mixture in water/methanol (50/50) produced mainly cobalt-cationized species. Three main groups of the Co-cationized species can be distinguished in the ESI-MS spectrum: (1) the cobalt complexes including the cysteine amino acid only (they can be
Massimiliano Aschi et al.
Journal of mass spectrometry : JMS, 44(7), 1038-1046 (2009-04-01)
The nature of the ionic species, formed by electrospray ionization (ESI) of Co(NO3)2/CH3OH solutions with a pair of aminoalcohols W and Y, has been investigated by mass spectrometric and computational methods. Collision induced dissociation (CID) of ions, formally corresponding to
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