Pular para o conteúdo
Merck
Todas as fotos(3)

Documentos Principais

243469

Sigma-Aldrich

Zinc

Zinc

granular, 20-30 mesh, ACS reagent, ≥99.8%

Sinônimo(s):

Zn

Faça loginpara ver os preços organizacionais e de contrato

Selecione um tamanho

100 G
R$ 417,00
500 G
R$ 1.302,00
2 KG
R$ 2.840,00

R$ 417,00


Disponível para enviar em07 de abril de 2025Detalhes


Solicite uma grande encomenda

Selecione um tamanho

Alterar visualização
100 G
R$ 417,00
500 G
R$ 1.302,00
2 KG
R$ 2.840,00

About This Item

Fórmula empírica (Notação de Hill):
Zn
Número CAS:
Peso molecular:
65.39
Número CE:
Número MDL:
Código UNSPSC:
12161600
ID de substância PubChem:
NACRES:
NA.22

R$ 417,00


Disponível para enviar em07 de abril de 2025Detalhes


Solicite uma grande encomenda

grau

ACS reagent

Nível de qualidade

pressão de vapor

1 mmHg ( 487 °C)

Ensaio

≥99.8%

Formulário

granular

adequação da reação

core: zinc
reagent type: catalyst

resistividade

5.8 μΩ-cm, 20°C

tamanho de partícula

20-30 mesh

p.e.

907 °C (lit.)

pf

420 °C (lit.)

densidade

7.133 g/mL at 25 °C (lit.)

traços de cátion

Fe: ≤0.01%
Pb: ≤0.01%

adequação

passes application test for determination of arsenic (As)

cadeia de caracteres SMILES

[Zn]

InChI

1S/Zn

chave InChI

HCHKCACWOHOZIP-UHFFFAOYSA-N

Descrição geral

Zinc granules are pure metallic zinc in a granular form, they provide a high surface area for increased reactivity.[1] They serve as a reducing agent, catalyst, or precursor for various chemical reactions. Zinc granules are commonly used for synthesis of organometallic compounds. It reacts with organic halides to form alkyl or aryl zinc compounds, which serve as powerful nucleophiles in carbon-carbon bond formations. This reaction, known as the Barbier reaction, enables the introduction of diverse functional groups into organic molecules.[2]Zinc granules also find application in the synthesis of pharmaceuticals and fine chemicals. They can be employed in the reduction of functional groups like nitro, nitrile, or azide to their corresponding amines. Additionally, zinc granules are involved in other carbon-carbon bond forming reactions, such as the Reformatsky reaction and the Simmons-Smith reaction.[2]

Aplicação

Zinc granules can be used to prepare:

  • organozinc reagents commonly used in Negishi or Fukuyama couplings[3][4]
  • Reformatsky reagents[5][6]
  • Simmons-Smith reagents[7][8]

Pictogramas

Environment

Palavra indicadora

Warning

Frases de perigo

Declarações de precaução

Classificações de perigo

Aquatic Acute 1 - Aquatic Chronic 1

Código de classe de armazenamento

11 - Combustible Solids

Classe de risco de água (WGK)

WGK 2

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable

Equipamento de proteção individual

Eyeshields, Gloves, type N95 (US)


Escolha uma das versões mais recentes:

Certificados de análise (COA)

Lot/Batch Number

Não está vendo a versão correta?

Se precisar de uma versão específica, você pode procurar um certificado específico pelo número do lote ou da remessa.

Já possui este produto?

Encontre a documentação dos produtos que você adquiriu recentemente na biblioteca de documentos.

Visite a Biblioteca de Documentos

Os clientes também visualizaram

Slide 1 of 3

1 of 3

Zinc sticks

Supelco

1.08782

Zinc

Zinc metal NIST® SRM 683

NIST683

Zinc metal

Zinc nanopowder, 40-60 nm avg. part. size, ≥99% trace metals basis

Sigma-Aldrich

578002

Zinc

Reagents for Organic Synthesis
L. F. Fieser and M. Fieser
Reagents for Organic Synthesis, 1 (1967)
A scalable zinc activation procedure using dibal-h in a reformatsky reaction.
Girgis M J
Organic Process Research & Development, 13(6), 1094-1099 (2009)
Advanced Organic Chemistry: Reactions, Mechanisms, and Structure
March, J
Advanced Organic Chemistry (2007)
Use of activation methods for organozinc reagents.
Erdik E
Tetrahedron, 43(10), 2203-2212 (1987)
Highly efficient, general procedure for the preparation of alkylzinc reagents from unactivated alkyl bromides and chlorides.
Huo S
Organic Letters, 5(4), 423-425 (2003)

Questions

1–2 of 2 Questions  
  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Helpful?

Reviews

Active Filters

  1. 1 Ratings-Only Review

Nossa equipe de cientistas tem experiência em todas as áreas de pesquisa, incluindo Life Sciences, ciência de materiais, síntese química, cromatografia, química analítica e muitas outras.

Entre em contato com a assistência técnica