Pular para o conteúdo
Merck
Todas as fotos(1)

Documentos

8.18287

Sigma-Aldrich

Lithium iodide

anhydrous for synthesis

Sinônimo(s):

Lithium iodide

Faça loginpara ver os preços organizacionais e de contrato
Todas as fotos(1)

About This Item

Fórmula empírica (Notação de Hill):
ILi
Número CAS:
10377-51-2
Peso molecular:
133.85
Número MDL:
MFCD00011092
Código UNSPSC:
12352302
Número do índice EC:
233-822-5
NACRES:
NA.22

Nível de qualidade

200

forma

powder

pf

450 °C

solubilidade

soluble 1640 g/L

densidade

4 g/cm3 at 20 °C

densidade volumétrica

1000 kg/m3

temperatura de armazenamento

2-30°C

InChI

1S/HI.Li/h1H;/q;+1/p-1

chave InChI

HSZCZNFXUDYRKD-UHFFFAOYSA-M

Aplicação

Lithium iodide (LiI) can be used as a catalyst to synthesize:
  • N-alkyl 2-pyridone derivatives via O- to N-[1,3]-alkyl migration.
  • β-mannosides and β-rhamnosides from glycosyl hemiacetals via one-pot chlorination, iodination, and glycosylation reaction.

It can also be used as:
  • Solid electrolyte in the synthesis of Vycor glass/LiI composites applicable in the development of solid-state batteries.
  • Iodine source to synthesize primary, secondary, and bridgehead tertiary alkyl iodides by PPh3-catalyzed iododecarboxylation of aliphatic carboxylates.

Nota de análise

Assay (argentometric): ≥ 98.0 %
Water (K. F.): ≤ 0.50 %

Código de classe de armazenamento

13 - Non Combustible Solids

Classe de risco de água (WGK)

WGK 1

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable

Certificados de análise (COA)

Busque Certificados de análise (COA) digitando o Número do Lote do produto. Os números de lote e remessa podem ser encontrados no rótulo de um produto após a palavra “Lot” ou “Batch”.

Já possui este produto?

Encontre a documentação dos produtos que você adquiriu recentemente na biblioteca de documentos.

Visite a Biblioteca de Documentos

Imlirenla Pongener et al.
Chemical science, 12(29), 10070-10075 (2021-08-12)
Stereoselective β-mannosylation is one of the most challenging problems in the synthesis of oligosaccharides. Herein, a highly selective synthesis of β-mannosides and β-rhamnosides from glycosyl hemi-acetals is reported, following a one-pot chlorination, iodination, glycosylation sequence employing cheap oxalyl chloride, phosphine
Preparation of N-alkyl 2-pyridones via a lithium iodide promoted O- to N-alkyl migration: scope and mechanism
Sarah Z Tasker, et al.
The Journal of Organic Chemistry, 77(18), 8220-8230 (2012)
Ming-Chen Fu et al.
Organic letters, 22(21), 8572-8577 (2020-10-23)
Under irradiation of 456 nm blue light-emitting diodes, PPh3 catalyzes the iododecarboxylation of aliphatic carboxylic acid derived N-(acyloxy)phthalimide with lithium iodide as an iodine source. The reaction delivers primary, secondary, and bridgehead tertiary alkyl iodides in acetone solvent, and the
Sarah Z Tasker et al.
The Journal of organic chemistry, 77(18), 8220-8230 (2012-08-30)
An efficient and inexpensive LiI-promoted O- to N-alkyl migration of 2-benzyloxy-, 2-allyloxy-, and 2-propargyloxypyridines and heterocycles is reported. The reaction produces the corresponding N-alkyl 2-pyridones and analogues under green, solvent-free conditions in good to excellent yields (30 examples, 20-97% yield).
Nanostructured ionic conductors: A study of Vycor7930-LiI composites
Albert Stephanie, et al.
Materials Science and Engineering Technology, 150(3), 199-202 (2008)

Nossa equipe de cientistas tem experiência em todas as áreas de pesquisa, incluindo Life Sciences, ciência de materiais, síntese química, cromatografia, química analítica e muitas outras.

Entre em contato com a assistência técnica