I5400
Indole-5-carboxylic acid
99%
Sinônimo(s):
5-Carboxyindole
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About This Item
Fórmula empírica (Notação de Hill):
C9H7NO2
Número CAS:
Peso molecular:
161.16
Beilstein:
124391
Número CE:
Número MDL:
Código UNSPSC:
12352100
ID de substância PubChem:
NACRES:
NA.22
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Ensaio
99%
pf
211-213 °C (lit.)
cadeia de caracteres SMILES
OC(=O)c1ccc2[nH]ccc2c1
InChI
1S/C9H7NO2/c11-9(12)7-1-2-8-6(5-7)3-4-10-8/h1-5,10H,(H,11,12)
chave InChI
IENZCGNHSIMFJE-UHFFFAOYSA-N
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Descrição geral
Indole-5-carboxylic acid is an indole derivative. On electropolymerization, it affords electroactive polymer film of poly(indole-5-carboxylic-acid).[1] Different concentrations of indole-5-carboxylic acid in sulfuric acid solution has been investigated for the preventive action against mild steel corrosion.[2] On electropolymerization it affords a trimeric product. Characterization studies of the trimeric product by 1H NMR and various one- and two-dimensional NMR techniques have been reported.[3]
Aplicação
- Reactant for preparation of tryptophan dioxygenase inhibitors pyridyl-ethenyl-indoles, as potential anticancer immunomodulators
- Reactant for preparation of indolyl-quinolines via metal- and solvent-free autoxidative coupling reaction
- Reactant for preparation of anthranilic acids using bromamine-B oxidant and palladium chloride catalyst
- Reactant for synthesis of indirubin derivatives
- Reactant for preparation of amide conjugates with ketoprofen, as inhibitors of Gli1-mediated transcription in Hedgehog pathway
- Reactant for preparation of piperazine-bisamide analogs as human growth hormone secretagogue receptor antagonists for treatment of obesity
Indole-5-carboxylic acid is the suitable reagent used to study the intramolecular excited state proton transfer in indole-2-carboxylic acid and indole-5-carboxylic acid in various solvents in acidic, basic, and neutral media by steady state and time resolved fluorescence spectroscopy.[4] It may be used in the electrochemical synthesis of poly(indole-5-carboxylic acid) (PICA) films.[5]
Código de classe de armazenamento
13 - Non Combustible Solids
Classe de risco de água (WGK)
WGK 3
Ponto de fulgor (°F)
Not applicable
Ponto de fulgor (°C)
Not applicable
Equipamento de proteção individual
Eyeshields, Gloves, type N95 (US)
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Inhibitive action of indole-5-carboxylic acid towards corrosion of mild steel in deaerated 0.5 M sulfuric acid solutions.
Quartarone G, et al.
Applied Surface Science, 252(23), 8251-8257 (2006)
Electropolymerisation of indole-5-carboxylic acid.
GordonaMackintosh J and Andrew R.
J. Chem. Soc., Faraday, 90(8), 1121-1125 (1994)
Characterization of the unsymmetrical trimer of indole-5-carboxylic acid by proton NMR spectroscopy.
Mackintosh JG, et al.
Magnetic Resonance in Chemistry, 32(9), 559-561 (1994)
Electrodeposition of poly (indole-5-carboxylic acid) in boron trifluoride diethyl etherate containing additional diethyl ether.
Nie G, et al.
Electrochimica Acta, 52(24), 7097-7106 (2007)
Excited state proton transfer in indole-2-carboxylic acid and indole-5-carboxylic acid.
Bangal PR and Chakravorti S.
The Journal of Physical Chemistry A, 103(43), 8585-8594 (1999)
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