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D62209

Sigma-Aldrich

trans-1,2-Dichloroethylene

98%

Sinônimo(s):

trans-1,2-Dichloroethene, trans-Acetylene dichloride

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5 G
R$ 463,00
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5 G
R$ 463,00
25 G
R$ 1.459,00
100 G
R$ 4.309,00

About This Item

Fórmula linear:
ClCH=CHCl
Número CAS:
Peso molecular:
96.94
Beilstein:
1420761
Número CE:
Número MDL:
Código UNSPSC:
12352100
ID de substância PubChem:
NACRES:
NA.22

R$ 463,00


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pressão de vapor

5.16 psi ( 20 °C)

Nível de qualidade

Ensaio

98%

Formulário

liquid

Lim. expl.

12.8 %

índice de refração

n20/D 1.446 (lit.)

p.e.

48 °C (lit.)

pf

−50 °C (lit.)

densidade

1.257 g/mL at 25 °C (lit.)

cadeia de caracteres SMILES

Cl\C=C\Cl

InChI

1S/C2H2Cl2/c3-1-2-4/h1-2H/b2-1+

chave InChI

KFUSEUYYWQURPO-OWOJBTEDSA-N

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Descrição geral

trans-1,2-Dichloroethylene is an organic solvent used in freon cleaning agents. [1]

Aplicação

trans-1,2-Dichloroethylene can be involved in the synthesis of:
  • (E)-Chloroenynes by reacting with 1-alkyne and piperidine in the presence of PdCl2(PPh3)2 catalyst in ethyl ether as a solvent.[2]
  • (E)-3-trimethylsilyl-1-chloro-1-propene by reacting with trimethylsilylmethylmagnesium chloride (TMSCH2MgCl) in the presence of Co(II) or Co(III) acetylacetonate.[3]
  • trans-1,2-Bis(tri-n-butylstannyl)ethylene which is an important reagent for the synthesis of myriad of natural products.[4]
  • trans-1-Chloroalkenes by reacting with Grignard reagents in the presence of tetrakis(triphenylphosphine)nickel as catalyst.[5]

Pictogramas

FlameExclamation mark

Palavra indicadora

Danger

Frases de perigo

Classificações de perigo

Acute Tox. 4 Inhalation - Aquatic Chronic 3 - Flam. Liq. 2

Código de classe de armazenamento

3 - Flammable liquids

Classe de risco de água (WGK)

WGK 2

Ponto de fulgor (°F)

42.8 °F - closed cup

Ponto de fulgor (°C)

6.0 °C - closed cup

Equipamento de proteção individual

Eyeshields, Faceshields, Gloves


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Os clientes também visualizaram

Slide 1 of 3

1 of 3

Cobalt-catalyzed mono-coupling of R3SiCH2MgCl with 1, 2-dihalogenoethylene: a general route to γ-substituted (E)-allylsilanes.
Kamachi T, et al.
Tetrahedron Letters, 45(24), 4677-4679 (2004)
Developmental toxicity of inhaled trans-1, 2-dichloroethylene in the rat
Hurtt, et al.
Fundamental and Applied Toxicology, 20, 225-230 (1993)
Suzuki Coupling Reactions of (E)-and (Z)-Chloroenynes with Boronic Acids: Versatile Access to Functionalized 1, 3-Enynes
Tikad A, et al.
European Journal of Organic Chemistry, 2010(4), 725-731 (2010)
Preparation of trans-1, 2-bis(tributylstannyl) ethylene.
Corey EJ and Wollenberg RH
The Journal of Organic Chemistry, 40(25), 3788-3789 (1975)
A convenient preparation of trans(or cis)-1-chloroalkenes from trans(or cis)-1, 2-dichloroethylene: A new synthesis of the sex pheromone of lobesia botrana.
Ratovelomanana V and Linstrumelle G
Tetrahedron Letters, 22(4), 315-318 (1981)

Questions

1–2 of 2 Questions  
  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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