931845

GenOx-PJ

• Sinônimo(s): 3-Oxo-2-tosyl-2,3-dihydro-1H-1λ₃-benzo[d][1,2]iodazol-1-yl acetate
• Fórmula empírica (Notação de Hill): C₁₆H₁₄INO₅S
• Número CAS: 2243393-44-2
• Peso molecular: 459.26
• Número MDL: MFCD26961149
• Código UNSPSC: 12352200
• NACRES: NA.21

Propriedades

• Formulário: powder
• Nível de qualidade: 100
• pf: >300 °C
• grupo funcional: iodo
• temperatura de armazenamento: −20°C

Descrição

Aplicação

GenOx-PJ is an iodine(III) based oxidant developed by Genentech as part of a robust method of forming C-O bonds through direct coupling of carboxylic acids with alcohols. When used with a Ru(II) photocatalyst, GenOx-PJ is active in the decarboxylative coupling of a broad range of carboxylic acids--including primary, secondary, tertiary, as well as peptides--with alcohols. By this method, GenOx-PJ enables a direct approach in utilizing simple, readily available substrates to perform this type of coupling, and providing many synthetic applications.

Outras notas

A Platform for Decarboxylative Couplings via Photoredox Catalysis: Direct Access to Carbocations from Carboxylic Acids for Carbon−Oxygen Bond Formation

Informações de segurança

• Código de classe de armazenamento: 11 - Combustible Solids
• Classe de risco de água (WGK): WGK 3
• Ponto de fulgor (°F): Not applicable
• Ponto de fulgor (°C): Not applicable