735809

[2-(Di-tert-butylphosphinomethyl)-6-(diethylaminomethyl)pyridine]carbonylchlorohydridoruthenium(II)

• Sinônimo(s): Milstein Catalyst Precursor, [2-(Di-tert-butylphosphinomethyl)-6-(diethylaminomethyl)pyridine]ruthenium(II) chlorocarbonyl hydride
• Fórmula empírica (Notação de Hill): C₂₀H₃₆ClN₂OPRu
• Número CAS: 863971-62-4
• Peso molecular: 488.01
• Número MDL: MFCD16038117
• Código UNSPSC: 12352300
• ID de substância PubChem: 329765059
• NACRES: NA.22

Propriedades

• forma: powder
• adequação da reação: core: ruthenium; reagent type: catalyst
• características do produto alternativo mais ecológico: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• categoria alternativa mais ecológica: Aligned,
• cadeia de caracteres SMILES: Cl[RuH].[C-]#[O+].CCN(CC)Cc1cccc(CP(C(C)(C)C)C(C)(C)C)n1
• InChI: 1S/C19H35N2P.CO.ClH.Ru.H/c1-9-21(10-2)14-16-12-11-13-17(20-16)15-22(18(3,4)5)19(6,7)8;1-2;;;/h11-13H,9-10,14-15H2,1-8H3;;1H;;/q;;;+1;/p-1
• chave InChI: RZCAJPSOQUIHSH-UHFFFAOYSA-M

Descrição

Descrição geral

May contain up to 10% acetone and/or THF.

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Aplicação

Precursor to active Ru catalyst for the dehydrogenative coupling of amines and alcohols to form amide bonds.

Precursor to active ruthenium catalyst for greener amide bond formation by dehydrogenative coupling of amines and alcohols.

Direct Synthesis of Amides from Alcohols and Amines with Liberation of H2

Informações de segurança

• Pictogramas: GHS08,GHS07
• Palavra indicadora: Warning
• Frases de perigo: H319,H351
• Declarações de precaução: P281 - P305 + P351 + P338
• Classificações de perigo: Carc. 2 - Eye Irrit. 2
• Perigos de suplementos: EUH019
• Código de classe de armazenamento: 13 - Non Combustible Solids
• Classe de risco de água (WGK): WGK 3
• Ponto de fulgor (°F): Not applicable
• Ponto de fulgor (°C): Not applicable