731013

JackiePhos

95%

• Sinônimo(s): 2-{Bis[3,5-bis(trifluoromethyl)phenyl]phosphino}-3,6-dimethoxy -2′,4′,6′-triisopropyl-1,1′-biphenyl, Bis(3,5-bis(trifluoromethyl)phenyl)(2′,4′,6′- triisopropyl-3,6-dimethoxybiphenyl-2-yl)phosphine
• Fórmula empírica (Notação de Hill): C₃₉H₃₇F₁₂O₂P
• Número CAS: 1160861-60-8
• Peso molecular: 796.66
• Número MDL: MFCD17015286
• Código UNSPSC: 12352112
• ID de substância PubChem: 329764613
• NACRES: NA.22

Propriedades

• Ensaio: 95%
• Formulário: solid
• adequação da reação: reaction type: Cross Couplings; reagent type: ligand; reaction type: Buchwald-Hartwig Cross Coupling Reaction; reagent type: ligand; reaction type: C-X Bond Formation
• pf: 186-190 °C
• grupo funcional: phosphine
• cadeia de caracteres SMILES: COc1ccc(OC)c(c1P(c2cc(cc(c2)C(F)(F)F)C(F)(F)F)c3cc(cc(c3)C(F)(F)F)C(F)(F)F)-c4c(cc(cc4C(C)C)C(C)C)C(C)C
• InChI: 1S/C39H37F12O2P/c1-19(2)22-11-29(20(3)4)33(30(12-22)21(5)6)34-31(52-7)9-10-32(53-8)35(34)54(27-15-23(36(40,41)42)13-24(16-27)37(43,44)45)28-17-25(38(46,47)48)14-26(18-28)39(49,50)51/h9-21H,1-8H3
• chave InChI: KYTUFIMHJNRPLC-UHFFFAOYSA-N

Descrição

Aplicação

Catalyst for N-Arylation reactions

Buchwald Phosphine Ligands for chemical Synthesis

JackiePhos is a Buchwald′s phosphine ligand which can be used for the:

• glycosyl cross-coupling reaction of diaryliodonium triflates with anomeric stannanes to synthesize C-glycosides.[1]
• synthesis of gold-based catalyst complexes such as [Au(CH₃CN)(JackiePhos)][SbF₆][2] and [(JackiePhos)AuCl.[3]
• acylation of alkylcarbastannatranes.[4]
• synthesis of cyclic guanidines or cyclic ureas bearing dialkylaminomethyl groups in combination with Pd(acac)₂ as a catalyst.[5]

Informações de segurança

• Código de classe de armazenamento: 11 - Combustible Solids
• Classe de risco de água (WGK): WGK 3
• Ponto de fulgor (°F): Not applicable
• Ponto de fulgor (°C): Not applicable