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Sigma-Aldrich

1-Butyl-3-methylimidazolium hexafluorophosphate

≥97.0% (HPLC)

Sinônimo(s):

BMIMPF6

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5 G
R$ 1.055,00
50 G
R$ 2.498,00
250 G
R$ 7.758,00

About This Item

Fórmula empírica (Notação de Hill):
C8H15F6N2P
Número CAS:
Peso molecular:
284.18
Número MDL:
Código UNSPSC:
12352100
ID de substância PubChem:
NACRES:
NA.22

R$ 1.055,00


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Nível de qualidade

Ensaio

≥97.0% (HPLC)

Formulário

liquid

índice de refração

n20/D 1.411 (lit.)

densidade

1.38 g/mL at 20 °C (lit.)

cadeia de caracteres SMILES

F[P-](F)(F)(F)(F)F.CCCCn1cc[n+](C)c1

InChI

1S/C8H15N2.F6P/c1-3-4-5-10-7-6-9(2)8-10;1-7(2,3,4,5)6/h6-8H,3-5H2,1-2H3;/q+1;-1

chave InChI

IXQYBUDWDLYNMA-UHFFFAOYSA-N

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Descrição geral

BMIMPF6 is used as an efficient reaction medium for various synthetic and catalytic transformations.[1]

1-Butyl-3-methylimidazolium hexafluorophosphate is an imidazolium-based, hydrophobic, room temperature ionic liquid (RTIL).[2][3] It can be prepared by reacting 1-methylimidazole with chlorobutane.[4] Gaseous hydrofluorocarbons (HFCs) such as fluoromethane, fluoroethane and 1,1,2,2-tetrafluoroethane are soluble in BMIMPF6.[5]

Aplicação

1-Butyl-3-methylimidazolium hexafluorophosphate is an ionic liquid employed in many environmentally friendly reactions.

It can also be used as a medium for reactions such as:
  • Ring-closing metathesis of diene and enyne substrates in the presence of a novel recyclable ruthenium carbene complex.[6]
  • Nickel(II)acetylacetonate catalyzed oxidation of aromatic aldehydes to the corresponding acids using dioxygen as the oxidant.[7]
  • Lipase-catalyzed enantioselective acylation of allylic alcohols.[8]
  • Allylation of aldehydes using tetraallylstannane to yield homoallylic alcohols.[9]

Pictogramas

Exclamation mark

Palavra indicadora

Warning

Frases de perigo

Classificações de perigo

Eye Irrit. 2 - Skin Irrit. 2

Código de classe de armazenamento

10 - Combustible liquids

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable

Equipamento de proteção individual

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


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Certificados de análise (COA)

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Visite a Biblioteca de Documentos

T. Itoh et al.
Chemistry Letters (Jpn), 262-262 (2001)
J. Howarth et al.
Tetrahedron Letters, 41, 10319-10319 (2000)
Ionic liquids: a convenient solvent for environmentally friendly allylation reactions with tetraallylstannane.
Gordon C.
Chemical Communications (Cambridge, England), (15), 1431-1432 (1999)
1-Butyl-3-methylimidazolium Hexafluorophosphate ([Bmim] PF6)
Yao Q
eEROS (Encyclopedia of Reagents for Organic Synthesis) (2001)
Gaseous absorption of fluoromethane, fluoroethane, and 1, 1, 2, 2-tetrafluoroethane in 1-butyl-3-methylimidazolium hexafluorophosphate.
Shiflett MB and Yokozeki A.
Industrial & Engineering Chemistry Research, 45(18), 6375-6382 (2006)

Questions

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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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