697737

Tris-(8-hydroxyquinoline)aluminum

sublimed grade, 99.995% trace metals basis

• Sinônimo(s): 8-Hydroxyquinoline aluminum salt, Alq₃, Aluminum 8-hydroxyquinolinate, Aluminum oxinate, Tris-(8-hydroxyquinolinato)aluminum
• Fórmula empírica (Notação de Hill): C₂₇H₁₈AlN₃O₃
• Número CAS: 2085-33-8
• Peso molecular: 459.43
• Número CE: 218-227-0
• Número MDL: MFCD00191693
• Código UNSPSC: 12352103
• ID de substância PubChem: 329761948
• NACRES: NA.23

Propriedades

• grau: sublimed grade
• Nível de qualidade: 100
• Ensaio: 99.995% trace metals basis
• Formulário: solid
• perda: 0.5 wt. % loss on heating, 332°C (typical, TGA)
• pf: >300 °C (lit.); 411 °C (DSC)
• λmax: 259 nm
• fluorescência: λ_ex 390 nm; λ_em 519 nm
• Energia orbital: HOMO 5.8 eV ; LUMO 3.1 eV
• Desempenho do dispositivo OLED: ITO/MoO₃/NPD/Alq₃/BPhen/LiF/Al;
  • Color: green
  • Max. Luminance: 20000 Cd/m²
  • Max. EQE: 1.2 %
  • Turn-On Voltage: 2.8 V
  ; ITO/NPD/CBP:Ir(ppy)₃/BCP/Alq₃/Mg:Al;
  • Color: green
  • Max. Luminance: 100000 Cd/m²
  • Max. EQE: 8 %
  • Turn-On Voltage: 4.3 V
  ; ITO/NPD/TCTA/BCPO:Ir(piq)3 (7-8%)/BCP/Alq₃/LiF/Al;
  • Color: red
  • Max. Luminance: 24529 Cd/m²
  • Max. EQE: 17 %
  • Turn-On Voltage: 2.7 V
  ; ITO/NPD/TCTA/BCPO:Ir(ppy)₃ (7-8%)/BCP/Alq₃/LiF/Al;
  • Color: green
  • Max. Luminance: 207839 Cd/m²
  • Max. EQE: 21.6 %
  • Turn-On Voltage: 2.1 V
  ; ITO/m-MTDATA/NPD/TTPhPhB/Alq₃/LiF/Al;
  • Color: blue
  • Max. Luminance: 9100 Cd/m²
  • Max. EQE: 2.5 %
  • Turn-On Voltage: 3.2 V
• cadeia de caracteres SMILES: O([Al](Oc1cccc2cccnc12)Oc3cccc4cccnc34)c5cccc6cccnc56
• InChI: 1S/3C9H7NO.Al/c3*11-8-5-1-3-7-4-2-6-10-9(7)8;/h3*1-6,11H;/q;;;+3/p-3
• chave InChI: TVIVIEFSHFOWTE-UHFFFAOYSA-K

Descrição

Descrição geral

Tris(8-hydroxyquinoline)aluminum(III)(Alq₃) is a key green-light emitting and electron transport material for OLEDs.[1] A study reports the new crystalline phase d besides its, originally known, three other crystalline phases, α,β,γ. [2] It exhibits excellent chemical stability and high luminescence efficiencies.[3]

Aplicação

Key green-light emitting and electron transport material for OLEDs.

Thin films of tris(8-hydroxyquinoline) aluminum (Alq₃) can be used for organic electroluminescent devices.[2]

Informações de segurança

• Pictogramas: GHS07
• Palavra indicadora: Warning
• Frases de perigo: H315,H319,H335
• Declarações de precaução: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Classificações de perigo: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Órgãos-alvo: Respiratory system
• Código de classe de armazenamento: 11 - Combustible Solids
• Classe de risco de água (WGK): WGK 3
• Ponto de fulgor (°F): Not applicable
• Ponto de fulgor (°C): Not applicable
• Equipamento de proteção individual: dust mask type N95 (US), Eyeshields, Gloves