637998
Vinylboronic anhydride pyridine complex
95%
Sinônimo(s):
2,4,6-Trivinylcyclotriboroxane pyridine complex, Trivinyl-boroxin pyridine complex, Trivinylcyclotriboroxane pyridine complex
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1 G
R$ 556,00
5 G
R$ 1.898,00
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1 G
R$ 556,00
5 G
R$ 1.898,00
About This Item
Fórmula empírica (Notação de Hill):
C6H9B3O3 · C5H5N
Número CAS:
Peso molecular:
240.67
Número MDL:
Código UNSPSC:
12352103
ID de substância PubChem:
NACRES:
NA.22
Produtos recomendados
Ensaio
95%
Formulário
solid
temperatura de armazenamento
−20°C
cadeia de caracteres SMILES
c1ccncc1.C=Cb2ob(C=C)ob(C=C)o2
InChI
1S/C6H9B3O3.C5H5N/c1-4-7-10-8(5-2)12-9(6-3)11-7;1-2-4-6-5-3-1/h4-6H,1-3H2;1-5H
chave InChI
YLHJACXHRQQNQR-UHFFFAOYSA-N
Categorias relacionadas
Aplicação
Reagent used for
Reagent used for Preparation of
- Suzuki-Miyaura cross-coupling[1][2]
- Stereoselective synthesis via Palladium-catalyzed carboamination[3]
- Alkyl-connected 2-amino-6-vinylpurine (AVP) crosslinking agent to cytosine base in RNA[4]
- Kaiser oxime resin-derived palladacycle as a recoverable polymeric precatalyst in Suzuki-Miyaura cross-coupling reactions in aqueous media[5]
- Kinetic resolution of phosphoryl and sulfonyl esters of binaphthol derivatives via Pd-catalyzed alcoholysis of their vinyl ethers[6]
- Stereoselective isomerization of N-allyl aziridines into Z-enamines by using rhodium hydride catalysis[7]
- Kinetic resolution of axially chiral biaryl derivatives via palladium/chiral diamine ligand-catalyzed alcoholysis[8]
- Transition metal-catalyzed alkenylation of aziridines, cycloaddition and thermal rearrangement reactions[9]
- Intramolecular Heck reaction strategy for synthesis of functionalized tetrahydroanthracenes[10]
Reagent used for Preparation of
Palavra indicadora
Warning
Frases de perigo
Declarações de precaução
Classificações de perigo
Eye Irrit. 2
Código de classe de armazenamento
11 - Combustible Solids
Classe de risco de água (WGK)
WGK 3
Ponto de fulgor (°F)
176.0 °F - closed cup
Ponto de fulgor (°C)
80 °C - closed cup
Equipamento de proteção individual
dust mask type N95 (US), Eyeshields, Gloves
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Kinetic resolution of axially chiral 2,2'-dihydroxy-1,1'-biaryls by palladium-catalyzed alcoholysis.
Hiroshi Aoyama et al.
Journal of the American Chemical Society, 127(30), 10474-10475 (2005-07-28)
Palladium-diamine complexes catalyzed kinetic resolution of axially chiral 2,2'-dihydroxy-1,1'-biaryls by alcoholysis of vinyl ethers. The reaction proceeded with high selectivity for various kinds of biaryls. This process is applicable to not only binaphthols but also biphenols, which have been considered
Heinrich Rueeger et al.
Bioorganic & medicinal chemistry letters, 21(7), 1942-1947 (2011-03-11)
This Letter describes the de novo design of non-peptidic hydroxyethylamine (HEA) inhibitors of BACE-1 by elimination of P-gp contributing amide attachments. The predicted binding mode of the novel cyclic sulfone HEA core template was confirmed in a X-ray co-crystal structure.
Shadi Dalili et al.
Organic letters, 7(6), 1161-1164 (2005-03-12)
[reaction: see text] Straightforward methods for palladium-catalyzed alkenylation of aziridines with alkenyl halides and copper-catalyzed alkenylation of aziridines with alkenyl boronic acids have been developed. This methodology offers attractive alternatives to the known methods requiring activated alkenyl halides and acetylenes.
Kinetic resolution of phosphoryl and sulfonyl esters of 1,1'-bi-2-naphthol via Pd-catalyzed alcoholysis of their vinyl ethers
Sakuma, T.; et al.
Tetrahedron, 19, 1593-1599 (2008)
Yosuke Taniguchi et al.
Bioorganic & medicinal chemistry, 18(8), 2894-2901 (2010-03-30)
We have previously reported that the 2-amino-6-vinylpurine (AVP) nucleoside exhibits a highly efficient and selective crosslinking reaction toward cytosine and displayed an improved antisense inhibition in cultured cells. In this study, we further investigated the alkyl-connected AVP nucleoside analogs for
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