590231

Di(acetato)dicyclohexylphenylphosphinepalladium(II), polymer-bound FibreCat^®

Pd ~5 %, extent of labeling: 0.4-0.6 mmol/g PPH₃ ligand content loading

• Número CAS: 480445-43-0
• Número MDL: MFCD04118909
• Código UNSPSC: 12352103
• NACRES: NA.22

Propriedades

• linha de produto: FibreCat^®
• Nível de qualidade: 100
• Formulário: solid
• composição: Pd, ~5%
• adequação da reação: core: palladium; reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reaction type: solution phase peptide synthesis; reagent type: catalyst; reaction type: Coupling Reactions
• Extensão da rotulagem: 0.4-0.6 mmol/g PPH₃ ligand content loading
• cadeia de caracteres SMILES: [Pd+2].P(C3CCCCC3)(C2CCCCC2)c1ccccc1.[O-]C(=O)C.[O-]C(=O)C
• chave InChI: ZMMYBYFXUHUTSH-UHFFFAOYSA-L

Descrição

Aplicação

Supported catalyst used in Suzuki coupling of less reactive aryl chloride with boronic acids. This supported catalyst is generally more selective than the free homogeneous catalyst, and palladium leaching is very low (<2 ppm).[1]

The resin can also be recycled.

Informações legais

FibreCat is a registered trademark of Johnson Matthey PLC

Informações de segurança

• Código de classe de armazenamento: 11 - Combustible Solids
• Classe de risco de água (WGK): WGK 3
• Ponto de fulgor (°F): Not applicable
• Ponto de fulgor (°C): Not applicable
• Equipamento de proteção individual: Eyeshields, Gloves, type N95 (US)