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407704

Sigma-Aldrich

4-Methylmorpholine

purified by redistillation, ≥99.5%

Sinônimo(s):

NMM

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About This Item

Fórmula empírica (Notação de Hill):
C5H11NO
Número CAS:
109-02-4
Peso molecular:
101.15
Beilstein:
102719
Número CE:
203-640-0
Número MDL:
MFCD00006175
Código UNSPSC:
12352100
ID de substância PubChem:
24865480
NACRES:
NA.22

densidade de vapor

>1 (vs air)

pressão de vapor

18 mmHg ( 20 °C)

Ensaio

≥99.5%

forma

liquid

purificado por

glass distillation
redistillation

índice de refração

n20/D 1.435 (lit.)

pH

10.6 (20 °C, 50 g/L)

pb

115-116 °C/750 mmHg (lit.)

pf

−66 °C (lit.)

densidade

0.92 g/mL at 25 °C (lit.)

cadeia de caracteres SMILES

CN1CCOCC1

InChI

1S/C5H11NO/c1-6-2-4-7-5-3-6/h2-5H2,1H3

chave InChI

SJRJJKPEHAURKC-UHFFFAOYSA-N

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Descrição geral

4-Methylmorpholine is an economical cation useful for the preparation of morpholinium cation-based ionic liquids. The experimental FT-IR and FT-Raman spectra of 4-methylmorpholine has been recorded over the range 4000-400cm-1 and 3500-100cm-1 respectively. It undergoes fluorination with cobalt(III) fluoride to afford highly fluorinated morpholines, which were characterized by mass and NMR spectroscopy.

Aplicação

4-Methylmorpholine may be used in the preparation of N-ethyl-N-methylmorpholinium bis(trifluoromethanesulfonyl)imide.

Palavra indicadora

Danger

Frases de perigo

H225,H302,H314

Classificações de perigo

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B

Código de classe de armazenamento

3 - Flammable liquids

Classe de risco de água (WGK)

WGK 1

Ponto de fulgor (°F)

53.6 °F - closed cup - DIN 51755 Part 1

Ponto de fulgor (°C)

12 °C - closed cup - DIN 51755 Part 1

Equipamento de proteção individual

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Certificados de análise (COA)

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The fluorination of 4-methylmorpholine over cobalt (III) fluoride: The isolation and characterisation of some novel polyfluoro-4-methylmorpholines by mass spectrometry and nmr spectroscopy; the mechanism of the title reaction.
Rendell RW and Wright B.
Tetrahedron, 34(2), 197-203 (1978)
Ki-Sub Kim et al.
Chemical communications (Cambridge, England), (7)(7), 828-829 (2004-03-27)
Ionic liquids based on N-alkyl-N-methylmorpholinium salts have been synthesized and the physical and electrochemical characteristics of this family of ionic liquids have been investigated for use as electrolytes.
V Balachandran et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 97, 1101-1110 (2012-08-30)
The experimental FT-IR (4000-400 cm(-1)) and FT-Raman (3500-100 cm(-1)) spectra of 4-Methylmorpholine were recorded. The observed bands were interpreted with the aid of normal coordinate analysis and force field calculations based on density functional theory (DFT) using B3LYP functional theory
L Hansén et al.
Scandinavian journal of work, environment & health, 12(1), 66-69 (1986-02-01)
The N-methylmorpholine levels in workroom air in a polyurethane foam factory were determined by two methods in which midget impinger flasks were used for sampling. The analyses were performed by gas chromatography and isotachophoresis. The values obtained by the gas
K Sitarek
Teratogenesis, carcinogenesis, and mutagenesis, 19(6), 369-376 (1999-12-10)
N-methylmorpholine, which is used as a catalyst in polyurethane foams producing, in solvents, stabilizing agents, and corrosion inhibitors, was administered to female rats by gavage at 100, 200, 600, and 900 mg/kg during organogenesis. It did not exhibit selective toxicity
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