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Sigma-Aldrich

Triisobutylamine

98%

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About This Item

Fórmula linear:
[(CH3)2CHCH2]3N
Número CAS:
1116-40-1
Peso molecular:
185.35
Beilstein:
1698950
Número CE:
214-236-9
Número MDL:
MFCD00040501
Código UNSPSC:
12352100
ID de substância PubChem:
24863352
NACRES:
NA.22

Ensaio

98%

índice de refração

n20/D 1.423 (lit.)

pb

192-193 °C/770 mmHg (lit.)

densidade

0.766 g/mL at 25 °C (lit.)

cadeia de caracteres SMILES

CC(C)CN(CC(C)C)CC(C)C

InChI

1S/C12H27N/c1-10(2)7-13(8-11(3)4)9-12(5)6/h10-12H,7-9H2,1-6H3

chave InChI

IIFFFBSAXDNJHX-UHFFFAOYSA-N

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Descrição geral

Triisobutylamine is a sterically hindered amine. The rate constants for H-atom abstraction from triisobutylamine has been evaluated.
Triisobutylamine is an organic base. Solubility and liquid-liquid equilibria of binary mixtures of triisobutylamine and water has been evaluated.

Aplicação

Triisobutylamine is suitable to develop second generation ionic liquid matrices for MALDI-MS of peptides, proteins and carbohydrates. It may be used in the separation of cis-fatty acid salts and and trans-fatty acid (elaidic acid) salts using a new organic solvent nanofiltration membrane based on polydicyclopentadiene. It may be used as base in the synthesis of acroyl ammonium derivatives.

Palavra indicadora

Danger

Classificações de perigo

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Irrit. 2

Código de classe de armazenamento

3 - Flammable liquids

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

134.6 °F - closed cup

Ponto de fulgor (°C)

57 °C - closed cup

Equipamento de proteção individual

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Certificados de análise (COA)

Busque Certificados de análise (COA) digitando o Número do Lote do produto. Os números de lote e remessa podem ser encontrados no rótulo de um produto após a palavra “Lot” ou “Batch”.

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Diisobutylamine

Synthesis of a Fused ?-Lactone via Pyridine-Assisted [2+ 2] Cycloaddition.
Reddy LR and Corey EJ.
Synfacts, 06, 0550-0550 (2006)
IUPAC-NIST Solubility Data Series. 96. Amines with Water Part 2. C7-C24 Aliphatic Amines.
Goral M, et al.
Journal of Physical and Chemical Reference Data, 41(4), 043107-043107 (2012)
Nicholas A Isley et al.
Journal of the American Chemical Society, 135(47), 17707-17710 (2013-11-15)
New technology has been developed that enables Suzuki-Miyaura couplings involving widely utilized MIDA boronates to be run in water as the only medium, mainly at room temperature. The protocol is such that no organic solvent is involved at any stage;
Jeffrey A Crank et al.
Journal of the American Society for Mass Spectrometry, 20(10), 1790-1800 (2009-08-12)
Second generation ionic liquid matrices are developed, examined, and tested. They have shown a wide mass detection range (<1000 Da to >270,000 Da) for proteins and peptides with greater S/N ratios than solid matrices. These ionic liquid matrices also exhibit
Abhinaba Gupta et al.
ACS applied materials & interfaces, 5(3), 924-933 (2013-01-04)
This article describes the separation of mixtures of fatty acid salts using a new organic solvent nanofiltration membrane based on polydicyclopentadiene (PDCPD). Mixtures of free fatty acids could not be separated by the membranes because they permeated at similar rates.
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