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209686
Iridium
powder, 99.9% trace metals basis
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500 MG
R$ 1.638,00
About This Item
Fórmula empírica (Notação de Hill):
Ir
Número CAS:
Peso molecular:
192.22
Número CE:
Número MDL:
Código UNSPSC:
12141720
ID de substância PubChem:
NACRES:
NA.23
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Nível de qualidade
Ensaio
99.9% trace metals basis
Formulário
powder
resistividade
4.71 μΩ-cm
p.e.
4130 °C (lit.)
pf
2450 °C (lit.)
densidade
22.65 g/cm3 (lit.)
cadeia de caracteres SMILES
[Ir]
InChI
1S/Ir
chave InChI
GKOZUEZYRPOHIO-UHFFFAOYSA-N
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Descrição geral
Iridium is a rare and dense transition metal that belongs to the platinum group of metals and is known for its remarkable physical and chemical properties. Iridium is used in high-temperature applications such as crucibles for crystal growth and in devices that operate under extreme conditions due to its high melting point and stability at elevated temperatures. It is also used in electrical contacts and electrodes because of its excellent corrosion resistance and electrical conductivity. In addition, iridium is used as a catalyst in various organic reactions including hydrogenation, water splitting, C-C coupling, and olefin metathesis.
Aplicação
- Iridium-based double perovskites for efficient water oxidation in acid media: This study highlights the development of iridium-based double perovskites that reduce iridium content while maintaining high activity and stability for water oxidation, significant for energy-related applications in material science (Diaz-Morales et al., 2016).
- Recent advances in understanding oxygen evolution reaction mechanisms over iridium oxide: This paper provides insights into the oxygen evolution reaction (OER) mechanisms on iridium oxide, crucial for improving catalytic processes in industrial applications (Naito et al., 2021).
- Iridium oxide fabrication and application: A review: A comprehensive review that discusses various methods for the fabrication of iridium oxides and their applications, particularly in sensors and catalysts, relevant to both drug discovery and material science (Chen et al., 2020).
Palavra indicadora
Danger
Frases de perigo
Declarações de precaução
Classificações de perigo
Flam. Sol. 1
Código de classe de armazenamento
4.1B - Flammable solid hazardous materials
Classe de risco de água (WGK)
nwg
Ponto de fulgor (°F)
Not applicable
Ponto de fulgor (°C)
Not applicable
Equipamento de proteção individual
Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
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Dik-Lung Ma et al.
PloS one, 8(2), e55751-e55751 (2013-03-05)
A cell permeable cyclometalated iridium(III) complex has been developed as a phosphorescent probe for cell imaging. The iridium(III) solvato complex [Ir(phq)2(H2O]2)] preferentially stains the cytoplasm of both live and dead cells with a bright luminescence.
Le Guo et al.
Organic letters, 15(5), 1144-1147 (2013-02-16)
The first α-alkylation of unactivated amides with primary alcohols is described. An effective and robust iridium pincer complex has been developed for selective α-alkylation of tertiary and secondary acetamides involving a "borrowing hydrogen" methodology. The method is compatible with alcohols
José Luis Núñez-Rico et al.
Organic letters, 15(8), 2066-2069 (2013-04-12)
Iridium(I) complexes of enantiomerically pure phosphine-phosphite ligands ([Ir(Cl)(cod)(P-OP)]) efficiently catalyze the enantioselective hydrogenation of diverse C═N-containing heterocyclic compounds (benzoxazines, benzoxazinones, benzothiazinones, and quinoxalinones; 25 examples, up to 99% ee). A substrate-to-catalyst ratio as high as 2000:1 was reached.
Yuyang Zhou et al.
Chemical communications (Cambridge, England), 49(31), 3230-3232 (2013-03-14)
Five iridium(III) complexes with two N-heterocyclic carbene (NHC) ligands and an ancillary ligand have been designed and successfully synthesized. With multicolor photoluminescence and low toxicity, these carbene complexes were tested, for the first time, as living cell imaging reagents and
Shiguang Pan et al.
Organic letters, 15(8), 1902-1905 (2013-04-02)
A cationic Ir(I) complex-catalyzed O-to-N-alkyl migration in 2-alkoxypyridines bearing a secondary alkyl group on the oxygen atom by C-O bond cleavage is described. The present transformation gave various N-alkylpyridones in moderate to good yields. The addition of sodium acetate played
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