325473

Selenium dioxide

reagent grade, powder, 98%

• Sinônimo(s): NSC 56753, Selenium oxide
• Fórmula linear: SeO₂
• Número CAS: 7446-08-4
• Peso molecular: 110.96
• Número CE: 231-194-7
• Número MDL: MFCD00003562
• Código UNSPSC: 12352303
• ID de substância PubChem: 24859512
• NACRES: NA.22
• Formulário: powder
• Ensaio: 98%

Propriedades

• grau: reagent grade
• Nível de qualidade: 200
• pressão de vapor: 1 mmHg ( 157 °C)
• Ensaio: 98%
• Formulário: powder
• adequação da reação: reagent type: oxidant
• cor: off-white to pink
• pf: 315 °C (subl.) (lit.)
• cadeia de caracteres SMILES: O=[Se]=O
• InChI: 1S/O2Se/c1-3-2
• chave InChI: JPJALAQPGMAKDF-UHFFFAOYSA-N

Descrição

Aplicação

Selenium dioxide (SeO₂) is mainly used to oxidize the α-methylene carbon atoms adjacent to a double bond to form allylic hydroxy derivatives.[1]
Other applications:

• SeO₂ reacts with olefins in the presence of tert-butyl hydrogen peroxide to form allylic alcohols without the formation of rearrangement or dehydration by-products.[2] This reagent system is also useful for the oxidation reactions of acetylenic fatty esters.[1]
• SeO₂ can be used for the oxidation of 1,3,5-cycloheptatriene to form tropone.[3]
• Piperidoindole systems on oxidation with SeO₂ forms either 2-acyl- or 3-acyl-indoles or fully aromatic β-carbolines, depending on the starting material.[4]
• SeO₂ reacts with chlorotrimethylsilane to form selenium oxychloride in situ, which is an effective chlorinating reagent for alcohols. This reagent is a better alternative to thionyl chloride and other chlorinating agents.[5]

Informações de segurança

• Pictogramas: GHS06,GHS08,GHS09
• Palavra indicadora: Danger
• Frases de perigo: H301 + H331,H373,H410
• Declarações de precaução: P260 - P264 - P273 - P301 + P310 - P304 + P340 + P311 - P314
• Classificações de perigo: Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2
• Código de classe de armazenamento: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• Classe de risco de água (WGK): WGK 2
• Ponto de fulgor (°F): Not applicable
• Ponto de fulgor (°C): Not applicable
• Equipamento de proteção individual: Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges