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Sigma-Aldrich

Propylene

≥99%

Sinônimo(s):

Propene

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About This Item

Fórmula linear:
CH3CH=CH2
Número CAS:
Peso molecular:
42.08
Beilstein:
1696878
Número CE:
Número MDL:
Código UNSPSC:
12142100
ID de substância PubChem:
NACRES:
NA.22

densidade de vapor

1.48 (vs air)

pressão de vapor

15.4 atm ( 37.7 °C)

Ensaio

≥99%

temperatura de autoignição

860 °F

Lim. expl.

11.1 %

pb

−47.7 °C (lit.)

pf

−185 °C (lit.)

cadeia de caracteres SMILES

CC=C

InChI

1S/C3H6/c1-3-2/h3H,1H2,2H3

chave InChI

QQONPFPTGQHPMA-UHFFFAOYSA-N

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Descrição geral

Propylene is a nonpolar olefin. It is commonly used as a precursor for the synthesis of cumene, propylene oxide,acrylonitrile, and isopropanol. Selective oxidation of propylene in a gas containing oxygen and hydrogen over Au/TiO2 catalysts has been reported. Polymerization of propylene using Ziegler-Natta catalyst has been studied. Metal-catalyzed copolymerizations of nonpolar olefins (ethylene and propylene) with alkyl acrylates has been described. Copolymerization of propylene with the linear α-olefins 1-octene, 1-decene, 1-tetradecene, and 1-octadecene has been studied.

Aplicação

Propylene may be used in the synthesis of propylene oxide via epoxidation with hydrogen peroxide, in the presence of titanium silicalite catalyst.

Embalagem

Supplied in a Sure/Pac cylinder and has a brass needle valve with a male 1/4" NPTF outlet thread installed. Before using the cylinder, ensure that the valve is closed, then remove the galvanized steel hex cap that seals the outlet valve.

Compatible with the following:

Informações legais

Aldrich is a registered trademark of Sigma-Aldrich Co. LLC
Sure/Pac is a trademark of Sigma-Aldrich Co. LLC

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Pictogramas

FlameGas cylinder

Palavra indicadora

Danger

Frases de perigo

Declarações de precaução

Classificações de perigo

Flam. Gas 1 - Press. Gas Liquefied gas

Código de classe de armazenamento

2A - Gases

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

-162.4 °F - closed cup

Ponto de fulgor (°C)

-108 °C - closed cup

Equipamento de proteção individual

Eyeshields, Faceshields, Gloves, multi-purpose combination respirator cartridge (US)


Certificados de análise (COA)

Busque Certificados de análise (COA) digitando o Número do Lote do produto. Os números de lote e remessa podem ser encontrados no rótulo de um produto após a palavra “Lot” ou “Batch”.

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Christian Schäfer et al.
Organic & biomolecular chemistry, 10(16), 3253-3257 (2012-03-13)
Intramolecular reductive coupling of cycloalkanones tethered to alkynoates in the presence of (η(2)-propene)titanium was successfully performed to provide hydroxy-esters in a diastereoselective manner. Subsequent lactonization afforded angularly fused unsaturated tricyclic lactones which represent relevant substructures of numerous bioactive compounds.
Thomas Hampel et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 18(33), 10382-10392 (2012-07-19)
The title compounds were synthesized in a longest sequence of 27 linear steps and with an overall yield of 2.9 and 3.9%. In the course of the synthesis, two aldehydes representing carbon fragments C1-C7 (Eastern fragment) and C9-C21 (Western fragment)
Jia Wei et al.
Journal of the American Chemical Society, 135(6), 2132-2135 (2013-01-25)
Modulation of steric interactions remote from the active sites within a series of dinuclear bis-propagators derived from racemic 2-4 was used to attenuate the rate of reversible chain transfer between active transition-metal centers and excess equivalents of inactive main-group-metal alkyl
Stefan Wuttke et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 18(38), 11959-11967 (2012-08-15)
A reducible MIL-100(Fe) metal-organic framework (MOF) was investigated for the separation of a propane/propene mixture. An operando methodology was applied (for the first time in the case of a MOF) in order to shed light on the separation mechanism. Breakthrough
The copolymerization of propylene with higher, linear a-olefins.
Van Reenen AJ, et al.
Journal of Polymer Science Part A: Polymer Chemistry, 38(22), 4110-4118 (2000)

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