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277053

Sigma-Aldrich

(S)-(+)-2-(Methoxymethyl)pyrrolidine

99%

Sinônimo(s):

O-Methyl-L-prolinol, SMP

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About This Item

Fórmula empírica (Notação de Hill):
C6H13NO
Número CAS:
63126-47-6
Peso molecular:
115.17
Beilstein:
3587324
Número MDL:
MFCD00010408
Código UNSPSC:
12352005
ID de substância PubChem:
24856730
NACRES:
NA.22

Ensaio

99%

forma

liquid

atividade óptica

[α]20/D +2.4°, c = 2 in benzene

índice de refração

n20/D 1.4457 (lit.)

pb

62 °C/40 mmHg (lit.)

densidade

0.933 g/mL at 25 °C (lit.)

cadeia de caracteres SMILES

COC[C@@H]1CCCN1

InChI

1S/C6H13NO/c1-8-5-6-3-2-4-7-6/h6-7H,2-5H2,1H3/t6-/m0/s1

chave InChI

CHPRFKYDQRKRRK-LURJTMIESA-N

Aplicação

(S)-(+)-2-(Methoxymethyl)pyrrolidine may be used to prepare planar chiral 2-phospha[3]ferrocenophanes. It may also be used as an organocatalyst in the cross-aldol reaction of dihydroxyacetone with p-nitrobenzaldehyde to form the corresponding polyol. SMP reacts with benzoylformic acid to form (S)-N-benzoylformyl-2-(methoxymethyl)-pyrrolidine.
Chiral auxiliary for asymmetric synthesis of propargyl alcohols and 4-nitrocyclohexanones, and for asymmetric Michael additions to enones.

Pictogramas

FlameExclamation mark
GHS02,GHS07

Palavra indicadora

Warning

Frases de perigo

H226,H315,H319,H335

Classificações de perigo

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

Órgãos-alvo

Respiratory system

Código de classe de armazenamento

3 - Flammable liquids

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

113.0 °F - closed cup

Ponto de fulgor (°C)

45 °C - closed cup

Equipamento de proteção individual

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Certificados de análise (COA)

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