Unfortunately, this product is not tested for purity.
227609
Decaborane(14)
white
Sinônimo(s):
Boron hydride, Decaborane, Decaboron tetradecahydride, NSC 39828, Tetradecahydrodecaborane, nido-Decaborane(14)
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About This Item
Fórmula linear:
B10H14
Número CAS:
Peso molecular:
122.22
Número CE:
Número MDL:
Código UNSPSC:
12352000
Preço e disponibilidade não estão disponíveis no momento.
Produtos recomendados
pressão de vapor
0.15 mmHg ( 20 °C)
Formulário
solid
adequação da reação
reagent type: reductant
cor
white
p.e.
213 °C (lit.)
pf
98-100 °C (lit.)
densidade
0.94 g/mL at 25 °C (lit.)
cadeia de caracteres SMILES
[BH]4321[BH]765[BH]984[BH]%11%103[BH]%13%122[BH]%1471[BH]%156([BH]%1695[BH]%118([H]%10)[H]%16)[BH]%14%13([H]%12)[H]%15
InChI
1S/B10H14/c11-5-1-2-3(1,5)7(2,9(3,5,11)13-7)8(2)4(1,2)6(1,5)10(4,8,12-6)14-8/h1-10H
chave InChI
XAMMYYSPUSIWAS-UHFFFAOYSA-N
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Categorias relacionadas
Aplicação
Boron source for ion-implantation processes.
Reactant for:
- Chemical vapor deposition of boron nitride nanosheets on Ni or Cu foils in the presence of ammonia
- Stereoselective catalytic hydrogenation reactions
- Chemical hydrogen storage
- Preparation of carborane-conjugated quinoline carboxamide ligands of translocator protein for boron neutron capture therapy (BNCT)
- Synthesis of hydrogenated boron clusters B12Hn with controlled hydrogen content
- Preparation of alkenyldecaboranes by regioselective transition-metal-catalyzed decaborane-alkyne hydroboration reactions
Palavra indicadora
Danger
Frases de perigo
Declarações de precaução
Classificações de perigo
Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Eye Irrit. 2 - Flam. Sol. 1 - Skin Irrit. 2 - STOT SE 3
Órgãos-alvo
Respiratory system
Código de classe de armazenamento
4.1B - Flammable solid hazardous materials
Classe de risco de água (WGK)
WGK 3
Ponto de fulgor (°F)
Not applicable
Ponto de fulgor (°C)
Not applicable
Equipamento de proteção individual
Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges, type P3 (EN 143) respirator cartridges
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Ilias Sioutis et al.
The journal of physical chemistry. A, 110(45), 12528-12534 (2006-11-10)
The interaction of decaborane (B(10)H(14)) with the I(-) ion and the (isoelectronic) Xe atom is investigated using a number of theoretical methods: MP2, CCSD(T), CCSD, spin-orbit CISD, and DFT using the B3LYP, B3PW91, PW91PW91, and PBE0 methods. All non-DFT and
Yuqi Li et al.
Inorganic chemistry, 47(20), 9193-9202 (2008-09-20)
Unlike in conventional organic solvents, where Lewis base catalysts are required, decaborane dehydrogenative alkyne-insertion reactions proceed rapidly in biphasic ionic-liquid/toluene mixtures with a wide variety of terminal and internal alkynes, thus providing efficient, one-step routes to functional o-carborane 1-R-1,2-C2B10H11 and
Zhu Yinghuai et al.
Journal of the American Chemical Society, 129(20), 6507-6512 (2007-05-03)
Well dispersed ruthenium(0) nanoparticles, stabilized in the ionic liquid agent, trihexyltetradecylphosphonium dodecylbenzenesulfonate, have been successfully prepared via a reduction reaction of the precursor [CpRuCp*RuCp*]PF6 (Cp* = C5Me5). The ruthenium(0) nanoparticles were shown to catalyze the isotope exchange reaction between 10B
Kiminori Ohta et al.
Bioorganic & medicinal chemistry letters, 14(23), 5913-5918 (2004-10-27)
We designed and synthesized novel retinoid X receptor (RXR)-selective antagonists bearing a carborane moiety. Compounds 8a-d or 9a-d themselves have no differentiation-inducing activity toward HL-60 cells and no inhibitory activity towards a retinoic acid receptor (RAR) agonist. However, they inhibit
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