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178837

Sigma-Aldrich

3-(Trimethylsilyl)-1-propanesulfonic acid sodium salt

97%

Sinônimo(s):

2,2-Dimethyl-2-silapentane-5-sulfonate sodium salt, DSS sodium salt, Sodium 3-(trimethylsilyl)-1-propanesulfonate

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About This Item

Fórmula linear:
(CH3)3Si(CH2)3SO3Na
Número CAS:
2039-96-5
Peso molecular:
218.32
Beilstein:
4035923
Número CE:
218-031-5
Número MDL:
MFCD00007537
Código UNSPSC:
12352100
ID de substância PubChem:
24850773
NACRES:
NA.22
Preço e disponibilidade não estão disponíveis no momento.

Nível de qualidade

100

Ensaio

97%

Formulário

solid

pf

~165 °C (dec.) (lit.)

grupo funcional

sulfonic acid

cadeia de caracteres SMILES

[Na+].C[Si](C)(C)CCCS([O-])(=O)=O

InChI

1S/C6H16O3SSi.Na/c1-11(2,3)6-4-5-10(7,8)9;/h4-6H2,1-3H3,(H,7,8,9);/q;+1/p-1

chave InChI

HWEXKRHYVOGVDA-UHFFFAOYSA-M

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Descrição geral

3-(Trimethylsilyl)-1-propanesulfonic acid sodium salt, also known as DSS sodium salt, is commonly used as an internal standard for referencing chemical shifts and scaling the intensity of all ¹H-NMR spectroscopy signals. [1]

Aplicação

3-(Trimethylsilyl)-1-propanesulfonic acid sodium salt can be used as a reagent to synthesize polyamine block-copolymers. It can also be used as an internal standard in 1H NMR spectroscopy for the measurement of chemical shifts.

Código de classe de armazenamento

11 - Combustible Solids

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable

Equipamento de proteção individual

Eyeshields, Gloves, type N95 (US)

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Certificados de análise (COA)

Lot/Batch Number
0000147201
0000358535
0000358536
MKCW6450
0000147201

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Radha Sharma et al.
Journal of pharmaceutical and biomedical analysis, 49(4), 1092-1096 (2009-03-21)
A rapid selective and accurate quantitative (1)H NMR method was developed for the simultaneous analysis of obidoxime chloride and atropine sulfate, the active components in parenteral injection devices (PID) used for the emergency treatment of poisoning by toxic organophosphates. The
J F Clark et al.
Biochimica et biophysica acta, 1014(3), 235-238 (1989-12-14)
3-(Trimethylsilyl)propanesulfonic acid (TMSPS) is used as a water-soluble NMR frequency marker. It has its major resonance at 0.00 ppm relative to trimethylsilane, and smaller resonances at 0.62, 1.77 and 2.85 ppm. Its toxicity was tested by exposing contracted porcine carotid
Jerome Kretzschmar et al.
Inorganic chemistry, 59(7), 4244-4254 (2020-03-10)
The interactions between glutathione disulfide, GSSG, the redox partner and dimer of the intracellular detoxification agent glutathione, GSH, and hexavalent uranium, U(VI), were extensively studied by solution NMR (in D2O), complemented by time-resolved laser-induced fluorescence and IR spectroscopies. As expected
Nicole D Wagner et al.
Environmental toxicology and chemistry, 37(9), 2448-2457 (2018-06-20)
Anthropogenic activity is increasing the presence of contaminants that enter waterways through wastewater effluent and urban and/or agricultural runoff, generally in complex mixtures. Depending on the mode of action of the individual contaminant within the mixture, toxicity can occur due
Douglas V Laurents et al.
The Journal of biological chemistry, 280(5), 3675-3685 (2004-11-24)
The Alzheimer's Abeta40 peptide forms soluble oligomers that are extremely potent neurotoxins and strongly impede synapses function. In this study the formation and structure of the large, soluble, neurotoxic Abeta40 oligomer called "beta-ball" were characterized by two-dimensional NMR, circular dichroism
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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

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    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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