122831
2-Aminobenzyl alcohol
98%
Sinônimo(s):
2-(Hydroxymethyl)aniline
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10 G
R$ 311,00
25 G
R$ 555,00
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10 G
R$ 311,00
25 G
R$ 555,00
About This Item
Fórmula linear:
H2NC6H4CH2OH
Número CAS:
Peso molecular:
123.15
Beilstein:
1072211
Número CE:
Número MDL:
Código UNSPSC:
12352100
ID de substância PubChem:
NACRES:
NA.22
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Ensaio
98%
Formulário
solid
p.e.
162 °C/15 mmHg (lit.)
pf
81-83 °C (lit.)
grupo funcional
hydroxyl
cadeia de caracteres SMILES
Nc1ccccc1CO
InChI
1S/C7H9NO/c8-7-4-2-1-3-6(7)5-9/h1-4,9H,5,8H2
chave InChI
VYFOAVADNIHPTR-UHFFFAOYSA-N
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Descrição geral
2-Aminobenzyl alcohol is oxidatively cyclised with an array of ketones in dioxane at 80°C in the presence of a ruthenium catalyst and KOH to give corresponding quinolines[1]. It undergoes oxidation catalyzed by heterotrimetallic RuMnMn species on the hydrotalcite surface in the presence of O2 to yield 2-aminobenzaldehyde[2].
Aplicação
2-Aminobenzyl alcohol was used in the synthesis of ethyl 2-hydroxymethylcarbanilate[3].
Código de classe de armazenamento
11 - Combustible Solids
Classe de risco de água (WGK)
WGK 3
Ponto de fulgor (°F)
Not applicable
Ponto de fulgor (°C)
Not applicable
Equipamento de proteção individual
dust mask type N95 (US), Eyeshields, Gloves
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Heterotrimetallic RuMnMn species on a hydrotalcite surface as highly efficient heterogeneous catalysts for liquid-phase oxidation of alcohols with molecular oxygen.
Kohki Ebitani et al.
Angewandte Chemie (International ed. in English), 44(22), 3423-3426 (2005-04-30)
Ruthenium-catalysed oxidative cyclisation of 2-aminobenzyl alcohol with ketones: modified Friedlaender quinoline synthesis.
Cho CS, et al.
Chemical Communications (Cambridge, England), 24, 2576-2577 (2001)
N Sundaraganesan et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 61(3), 377-385 (2004-12-08)
The Fourier transform Raman and Fourier transform infrared spectra of 2-aminobenzyl alcohol (2ABA) were recorded in the solid phase. Geometry optimizations were done with out any constraint and harmonic vibrational wave numbers and several thermodynamic parameters were calculated for the
Facile intramolecular nucleophilic attack by alkoxide ions on ethyl and p-nitrophenyl carbamates.
J E Hutchins et al.
Journal of the American Chemical Society, 95(11), 3786-3790 (1973-05-30)
J P Chism et al.
Chemical research in toxicology, 2(3), 150-156 (1989-05-01)
Previous results have suggested that key intermediates in the activation of 2-nitrotoluene and 2,6-dinitrotoluene are 2-aminobenzyl alcohol and 2-amino-6-nitrobenzyl alcohol, respectively. In order to determine the metabolic pathway(s) involved in the activation steps, calf thymus DNA and [14C]-2-aminobenzyl alcohol or
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