10894

Hexachloro-2-propanone

Wacker Chemie AG, ≥99.0% (GC)

• Sinônimo(s): HCA, Hexachloroacetone
• Fórmula linear: CCl₃COCCl₃
• Número CAS: 116-16-5
• Peso molecular: 264.75
• Beilstein: 1707475
• Número CE: 204-129-5
• Número MDL: MFCD00000796
• Código UNSPSC: 12352100
• ID de substância PubChem: 57646830
• NACRES: NA.22

Propriedades

• Nível de qualidade: 100
• Ensaio: ≥99.0% (GC)
• fabricante/nome comercial: Wacker Chemie AG
• índice de refração: n20/D 1.511 (lit.)
• p.e.: 66-70 °C/6 mmHg (lit.)
• pf: −6-−2 °C (lit.)
• densidade: 1.743 g/mL at 25 °C (lit.)
• aplicação(ões): agriculture; environmental
• grupo funcional: chloro; ketone
• cadeia de caracteres SMILES: ClC(Cl)(Cl)C(=O)C(Cl)(Cl)Cl
• InChI: 1S/C3Cl6O/c4-2(5,6)1(10)3(7,8)9
• chave InChI: DOJXGHGHTWFZHK-UHFFFAOYSA-N

Descrição

Descrição geral

Hexachloro-2-propanone is a colorless liquid. It is present in herbicide Bromacil formulation. Hexachloro-2-propanone is precursor for the generation and cycloaddition of oxyallyl intermediates[1]. It reverts the Ames strains TA98 and TA100 but not the non-plasmid strains TA1537, TA1535 and TA1538[2].

Aplicação

Hexachloro-2-propanone (hexachloroacetone) was used in the synthesis of chirally deuterated benzyl chlorides[3] and enol phosphate 2,2-dichloro-1-(trichloromethyl)ethenyl diethyl phosphate[1]. It was also used in obtaining efficient amino acid activation by exploiting the rapid formation of acid chlorides under low temperature and acid/base free conditions[4].

Outras notas

prices for bulk quantities on request

Informações de segurança

• Pictogramas: GHS06,GHS09
• Palavra indicadora: Danger
• Frases de perigo: H302,H317,H331,H411
• Declarações de precaução: P261 - P273 - P280 - P301 + P312 - P302 + P352 - P304 + P340 + P311
• Classificações de perigo: Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2 - Skin Sens. 1
• Código de classe de armazenamento: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• Classe de risco de água (WGK): WGK 2
• Ponto de fulgor (°F): 235.4 °F - closed cup
• Ponto de fulgor (°C): 113 °C - closed cup
• Equipamento de proteção individual: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter