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93000

Sigma-Aldrich

Trityl chloride

purum, ≥97.0% (HPLC), ≥97.0% (AT)

Synonyme(s) :

Chlorotriphenylmethane, Triphenylchloromethane, Triphenylmethyl chloride

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About This Item

Formule linéaire :
(C6H5)3CCl
Numéro CAS:
76-83-5
Poids moléculaire :
278.78
Numéro Beilstein :
397363
Numéro CE :
200-986-4
Numéro MDL:
MFCD00000813
Code UNSPSC :
12352101
ID de substance PubChem :
329770191
Nomenclature NACRES :
NA.22

Qualité

purum

Niveau de qualité

200

Pureté

≥97.0% (AT)
≥97.0% (HPLC)

Forme

powder

Résidus de calcination

≤0.2% (as SO4)

Point d'ébullition

230-235 °C/20 mmHg (lit.)

Pf

109-112 °C (lit.)
109-113 °C

Solubilité

chloroform: 0.1 g/mL, clear

Chaîne SMILES 

ClC(c1ccccc1)(c2ccccc2)c3ccccc3

InChI

1S/C19H15Cl/c20-19(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H

Clé InChI

JBWKIWSBJXDJDT-UHFFFAOYSA-N

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Catégories apparentées

Application

  • Organic Synthesis: Research on the synthesis of 1, 2, 4-triazine derivatives, exploring the condensation reactions of trityl chloride with various compounds (Majid et al., 2020).

Autres remarques

Reagent for tritylations;; Efficient method of tritylation of sensitive compounds and their subsequent detritylation

Pictogrammes

Corrosion
GHS05

Mention d'avertissement

Danger

Mentions de danger

H314

Classification des risques

Skin Corr. 1B

Code de la classe de stockage

8A - Combustible corrosive hazardous materials

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable

Équipement de protection individuelle

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificats d'analyse (COA)

Lot/Batch Number
WXBF3742V
WXBF2663V
BCCK8945
WXBF2119V
BCCK3781

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J S Davidson et al.
Biochimica et biophysica acta, 847(1), 1-7 (1985-10-30)
Intercellular junctional communication was measured using [14C]citrulline incorporation in co-cultures of argininosuccinate synthetase-deficient and argininosuccinate lyase-deficient human fibroblasts. Triphenylmethane, triphenylmethylchloride and tetraphenylboron inhibited communication at concentrations at least 12-fold lower than cytotoxic concentrations. This inhibition was of rapid onset and
S J Harding et al.
Journal of peptide science : an official publication of the European Peptide Society, 5(8), 368-373 (1999-10-03)
A rational attempt to prepare FmocHis(piTrt)OH regiospecifically gave in fact the well-known tau-trityl isomer, and experiments with model systems indicate that the prospects for access to pi-trityl histidine derivatives, which would be of great value for the racemization-free synthesis of
Vijayavitthal T Mathad et al.
Natural product research, 20(12), 1053-1058 (2006-11-28)
Jones oxidation of Andrographolide (1), gave mixture of three products (3-dehydroandrographolide (5), 3,19-bis dehydroandrographolide (6) and 19-dehydroandrographolide (7). Tritylation of andrographolide at C19-OH resulted to products 8 and diene 9, which can be converted to its acetate 10 and oxidation
R Hasegawa et al.
Regulatory toxicology and pharmacology : RTP, 47(3), 296-307 (2006-12-13)
We comprehensively re-analyzed the toxicity data for 18 industrial chemicals from repeated oral exposures in newborn and young rats, which were previously published. Two new toxicity endpoints specific to this comparative analysis were identified, the first, the presumed no observed
Ryuichi Hasegawa et al.
Congenital anomalies, 45(4), 137-145 (2005-12-20)
To elucidate the comparative susceptibility of newborn rats to chemicals, newborn and young animals were administered six industrial chemicals by gavage from postnatal days (PND) 4 to 21, and for 28 days starting at 5-6 weeks of age respectively, under
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