Direkt zum Inhalt
Merck
  • Synthesis of indenes via Brønsted acid catalyzed cyclization of diaryl- and alkyl aryl-1,3-dienes.

Synthesis of indenes via Brønsted acid catalyzed cyclization of diaryl- and alkyl aryl-1,3-dienes.

Organic letters (2012-10-26)
Dahan Eom, Sangjune Park, Youngchul Park, Taekyu Ryu, Phil Ho Lee
ZUSAMMENFASSUNG

Substituted indenes can be synthesized via the Brønsted acid catalyzed cyclization of diaryl- and alkyl aryl-1,3-dienes. In this approach, treatment of symmetric or unsymmetric diaryl- and alkyl aryl-1,3-dienes with a catalytic amount of trifluoromethanesulfonic acid gives a variety of indene derivatives in good to excellent yields under mild conditions.

MATERIALIEN
Produktnummer
Marke
Produktbeschreibung

Sigma-Aldrich
Zinktrifluormethansulfonat, 98%
Sigma-Aldrich
Trifluormethansulfonsäure, ReagentPlus®, ≥99%
Sigma-Aldrich
Silbertrifluormethansulfonat, ≥99%
Sigma-Aldrich
Aluminiumtrifluormethansulfonat, 99.9% trace metals basis
Sigma-Aldrich
Lithiumtrifluormethansulfonat, 99.995% trace metals basis
Sigma-Aldrich
Silbertrifluormethansulfonat, ≥99.95% trace metals basis
Sigma-Aldrich
Lanthan(III)-trifluormethansulfonat, 99.999% trace metals basis
Sigma-Aldrich
Trifluormethansulfonsäure, reagent grade, 98%
Sigma-Aldrich
Lithiumtrifluormethansulfonat, 96%
Sigma-Aldrich
Silbertrifluormethansulfonat, purum, ≥98.0% (Ag)