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Merck

18649

Sigma-Aldrich

Siliziumdioxid

acid washed

Synonym(e):

Cristobalit, Kieselgel, Quarz, Seesand

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About This Item

Lineare Formel:
SiO2
CAS-Nummer:
Molekulargewicht:
60.08
MDL-Nummer:
UNSPSC-Code:
12352303
PubChem Substanz-ID:
NACRES:
SB.52

Form

solid

Qualität

acid washed

Verunreinigungen

≤0.01% in acid soluble iron (Fe)
≤0.5% soluble in HCl

Verlust

≤0.5% loss on ignition, 800 °C

Brechungsindex

n20/D 1.544 (lit.)

mp (Schmelzpunkt)

1610 °C (lit.)

Dichte

2.6 g/mL at 25 °C (lit.)

Anionenspuren

chloride (Cl-): ≤100 mg/kg

SMILES String

O=[Si]=O

InChI

1S/O2Si/c1-3-2

InChIKey

VYPSYNLAJGMNEJ-UHFFFAOYSA-N

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Allgemeine Beschreibung

Silicon dioxide (SiO2) exists in three crystalline forms, namely quartz, tridymite and cristobalite. It reacts with hydrofluoric acid to form silicon tetrafluoride (SiF4) and water. Silicates are formed on reacting SiO2 with alkali melts. SiO2 is the main component in glass, brick and concrete and also forms the insulator in silicon devices. The alteration of the surface of SiO2 with (3-aminopropyl)triethoxysilane (APTES) for binding lactate dehydrogenase (LDH) to form an amino layer has been reported. The silicon-silicon dioxide structure has been investigated at liquid nitrogen temperature by electron spin resonance spectra.

Anwendung

Silicon dioxide may be used to produce silicon by electrochemical reduction in the presence of calcium chloride (CaCl2) electrolyte. It may also be used to prepare FeCl3/SiO2, a supported reagent for the oxidative coupling reactions.

Lagerklassenschlüssel

11 - Combustible Solids

WGK

nwg

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Persönliche Schutzausrüstung

Eyeshields, Gloves, type N95 (US)


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Iron trichloride/silicon dioxide reacts as oxidant or Lewis acid with phenol ethers.
Jempty TC, et al.
The Journal of Organic Chemistry, 46(22), 4545-4551 (1981)
Study of silicon-silicon dioxide structure by electron spin resonance I.
Nishi Y.
Japanese Journal of Applied Physics, 10(1), 52-52 (1971)
Pinpoint and bulk electrochemical reduction of insulating silicon dioxide to silicon.
Nohira T, et al.
Nature Materials, 2(6), 397-401 (2003)
Electronic structure of silicon dioxide (a review).
Nekrashevich SS and Gritsenko VA.
Physics of the Solid State, 56(2), 207-222 (2014)
Surface modification of silicon dioxide, silicon nitride and titanium oxynitride for lactate dehydrogenase immobilization.
Saengdee P, et al.
Biosensors And Bioelectronics, 67, 134-138 (2015)

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