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Merck

24004-M

Sigma-Aldrich

Diethylether

≥99.5% (GC), puriss, contains ~5 mg/L 2, 6-di-tert.-butyl-4-methylphenol as stabilizer, meets analytical specification of Ph. Eur., BP

Synonym(e):

Ether, Ethylether

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About This Item

Lineare Formel:
(CH3CH2)2O
CAS-Nummer:
Molekulargewicht:
74.12
Beilstein:
1696894
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12352112
PubChem Substanz-ID:
NACRES:
NA.21

product name

Diethylether, puriss., contains ~5 mg/L 2,6-di-tert.-butyl-4-methylphenol as stabilizer, meets analytical specification of Ph. Eur., BP, ≥99.5% (GC)

Dampfdichte

2.6 (vs air)

Qualität

puriss.
meets analytical specification of Ph. Eur., BP

Assay

≥99.5% (GC)

Form

liquid

Selbstzündungstemp.

320 °F

Enthält

~5 mg/L 2,6-di-tert.-butyl-4-methylphenol as stabilizer

Expl.-Gr.

36.5 %

Verunreinigungen

acidic reac. Impurities, in accordance
aldehydes, in accordance
residual solvents, in accordance
≤0.0002% peroxides (as H2O2)
≤0.002% free acid (as CH3COOH)
≤0.002% non-volatile matter
≤0.2% water (Karl Fischer)

Brechungsindex

n20/D 1.3530 (lit.)

bp

34.6 °C (lit.)

mp (Schmelzpunkt)

−116 °C (lit.)

Dichte

0.706 g/mL at 25 °C (lit.)

SMILES String

CCOCC

InChI

1S/C4H10O/c1-3-5-4-2/h3-4H2,1-2H3

InChIKey

RTZKZFJDLAIYFH-UHFFFAOYSA-N

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Anwendung

Diethyl ether can be used as a solvent:
  • In the catalytic depolymerization of alkali lignin to yield monomeric phenolic compounds.
  • To synthesize aziridines via aza-Darzens reaction.
  • In the catalytic hydrogenation of aldehydes to alcohols.

Piktogramme

FlameExclamation mark

Signalwort

Danger

Gefahreneinstufungen

Acute Tox. 4 Oral - Flam. Liq. 1 - STOT SE 3

Zielorgane

Respiratory system

Zusätzliche Gefahrenhinweise

Lagerklassenschlüssel

3 - Flammable liquids

WGK

WGK 1

Flammpunkt (°F)

-40.0 °F - closed cup

Flammpunkt (°C)

-40.00 °C - closed cup


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Die Dokumentenbibliothek aufrufen

A study on the catalytic hydrogenation of aldehydes using mayenite as active support for palladium
Proto A, et al.
Catalysis Communications, 68, 41-45 (2015)
Asymmetric aziridine synthesis by aza-Darzens reaction of N-diphenylphosphinylimines with chiral enolates. Part 1: Formation of cis-aziridines
Sweeney J, et al.
Tetrahedron, 62, 3681-3693 (2006)
Catalytic depolymerization of alkali lignin in subcritical water: influence of formic acid and Pd/C catalyst on the yields of liquid monomeric aromatic products
Onwudili J, et al.
Green Chemistry, 16, 4740-4748 (2014)
K H Young et al.
Journal of clinical microbiology, 10(6), 852-853 (1979-12-01)
Ethyl acetate appears to be a satisfactory subsitute solvent for diethyl ether in the Formalin-ether sedimentation technique. In comparative studies, concentration of organisms with ethyl acetate was equal to or greater than that with diethyl ether. No distortion or alteration

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