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Merck

E45260

Sigma-Aldrich

Woodward-Reagenz K

95%

Synonym(e):

2-Ethyl-5-phenyl-isoxazolium-3′-sulfonat, NEPIS

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About This Item

Empirische Formel (Hill-System):
C11H11NO4S
CAS-Nummer:
Molekulargewicht:
253.27
Beilstein:
4149224
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12352005
PubChem Substanz-ID:
NACRES:
NA.22

Assay

95%

Eignung der Reaktion

reaction type: Coupling Reactions

mp (Schmelzpunkt)

220 °C (dec.) (lit.)

Anwendung(en)

peptide synthesis

SMILES String

CC[n+]1ccc(o1)-c2cccc(c2)S([O-])(=O)=O

InChI

1S/C11H11NO4S/c1-2-12-7-6-11(16-12)9-4-3-5-10(8-9)17(13,14)15/h3-8H,2H2,1H3

InChIKey

MWOOKDULMBMMPN-UHFFFAOYSA-N

Lagerklassenschlüssel

11 - Combustible Solids

WGK

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable


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G Feller et al.
The Journal of biological chemistry, 271(39), 23836-23841 (1996-09-27)
Chloride is the allosteric effector of vertebrate pancreatic and salivary alpha-amylases and of the bacterial alpha-amylase from Alteromonas haloplanctis. Activation experiments of A. haloplanctis alpha-amylase by several monovalent anions show that a negative charge, not restricted to that of Cl-
S R Rao et al.
Indian journal of biochemistry & biophysics, 34(3), 253-258 (1997-06-01)
Maize leaf NADP-malic enzyme was rapidly inactivated by micromolar concentrations of Woodward's reagent K (WRK). The inactivation followed pseudo-first order reaction kinetics. The order of reaction with respect to WRK was 1, suggesting that inactivation was a consequence of the
Paulina Nawłoka et al.
Acta biochimica Polonica, 50(2), 567-572 (2003-07-02)
Effects of several chemical probes selectively modifying various amino-acid residues on the activity of UDP-glucose : solasodine glucosyltransferase from eggplant leaves was studied. It was shown that diethylpyrocarbonate (DEPC), a specific modifier of histidine residues, was strongly inhibitory. However, in
A R Johnson et al.
Protein science : a publication of the Protein Society, 5(2), 382-390 (1996-02-01)
L-Threonine dehydrogenase (TDH) from Escherichia coli is rapidly inactivated and develops a new absorbance peak at 347 nm when incubated with N-ethyl-5-phenylisoxazolium-3'-sulfonate (Woodward's reagent K, WRK). The cofactors, NAD+ or NADH (1.5 mM), provide complete protection against inactivation; L-threonine (60
P Paoli et al.
The Biochemical journal, 328 ( Pt 3), 855-861 (1998-02-07)
The organ common-type (CT) isoenzyme of acylphosphatase is inactivated by Woodward's reagent K (WRK) (N-ethyl-5-phenylisoxazolium-3'-sulphonate) at pH6.0. The inactivation reaction follows apparent pseudo first-order kinetics. The dependence of the reciprocal of the pseudo first-order kinetic constant (kobs) on the reciprocal

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