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A32608

Sigma-Aldrich

Allylglycidylether

≥99%

Synonym(e):

1-Allyloxy-2,3-epoxypropan, Allyl-2,3-epoxypropylether

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About This Item

Empirische Formel (Hill-System):
C6H10O2
CAS-Nummer:
106-92-3
Molekulargewicht:
114.14
Beilstein:
105871
EG-Nummer:
203-442-4
MDL-Nummer:
MFCD00005143
UNSPSC-Code:
12162002
PubChem Substanz-ID:
24890754
NACRES:
NA.23
Preise und Verfügbarkeit sind derzeit nicht verfügbar.

Dampfdichte

3.9 (vs air)

Qualitätsniveau

200

Dampfdruck

4.7 mmHg ( 25 °C)

Assay

≥99%

Form

liquid

Brechungsindex

n20/D 1.433 (lit.)

bp

154 °C (lit.)

Dichte

0.962 g/mL at 25 °C (lit.)

SMILES String

C=CCOCC1OC1

InChI

1S/C6H10O2/c1-2-3-7-4-6-5-8-6/h2,6H,1,3-5H2

InChIKey

LSWYGACWGAICNM-UHFFFAOYSA-N

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Allgemeine Beschreibung

Allyl glycidyl ether (AGE) is a monomer that acts as a building block in the polymerization of poly(allyl glycidyl ether) by anionic ring opening mechanism. It is industrially prepared by the reacting allyl alcohol and epichlorohydrin.[1][2]

Anwendung

Useful in hydrosilylation, including the H2PtCl6·xH2O (cat. no. 206083) catalyzed hydrosilylation of siloxanes to epoxysiloxanes.[3]
AGE can be used as a terminal epoxy group in the development of adhesive surfaces by hydrosilylation process.[4] It can also be used in the synthesis of polymeric electrolytes for the fabrication of lithium batteries.[5]

Signalwort

Danger

Gefahreneinstufungen

Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Carc. 2 - Eye Dam. 1 - Flam. Liq. 3 - Muta. 2 - Repr. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

Zielorgane

Respiratory system

Lagerklassenschlüssel

3 - Flammable liquids

WGK

WGK 3

Flammpunkt (°F)

134.6 °F - closed cup

Flammpunkt (°C)

57 °C - closed cup

Persönliche Schutzausrüstung

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Hier finden Sie alle aktuellen Versionen:

Analysenzertifikate (COA)

Lot/Batch Number
STBL3518
STBL4399
SDBB0561
STBL4243
STBL1786

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251747

2-Ethylhexylglycidylether

Poly(glycidylmethacrylat) Mn 10,000-20,000

Sigma-Aldrich

705314

Poly(glycidylmethacrylat)

3-Allyloxy-1,2-propandiol 99%

Sigma-Aldrich

251739

3-Allyloxy-1,2-propandiol

1,2-Epoxyhexan 97%

Sigma-Aldrich

377171

1,2-Epoxyhexan

Bhalchandra K Vaidya et al.
Bioresource technology, 99(9), 3623-3629 (2007-09-04)
Macroporous polymer particles containing surface epoxy groups were synthesized for immobilization of Candida rugosa lipase (CRL). The effect of incorporation of two different sets of monomers [allyl glycidyl ether (AGE) and glycidyl methacrylate (GMA)] and the effect of crosslinking density
Challa Lahari et al.
Langmuir : the ACS journal of surfaces and colloids, 26(2), 1096-1106 (2009-12-10)
Effects of changes in hydrophobicity of polymeric support on structure and activity of alpha-chymotrypsin (E.C. 3.4.21.1) have been studied with copolymers of allyl glycidyl ether (AGE) and ethylene glycol dimethacrylate (EGDM) with increasing molar ratio of EGDM to AGE (cross-link
A Dooms-Goossens et al.
Contact dermatitis, 33(1), 17-19 (1995-07-01)
We present a 43-year-old man who worked in the plastics industry and who suffered from an occupational dermatitis on the hands and forearms. He was found to be allergic to an epoxy silane compound that was contaminated with allyl glycidyl
Allyl glycidyl ether-based polymer electrolytes for room temperature lithium batteries
Barteau KP, et al.
Macromolecules, 46(22), 8988-8994 (2013)
Y Koyama et al.
Bioconjugate chemistry, 7(3), 298-301 (1996-05-01)
Novel poly(ethylene glycol) (PEG) derivatives having pendant amino groups were prepared by copolymerization of allyl glycidyl ether with ethylene oxide followed by chemical modification of the double bond side chains. Dropwise addition of the mixture of monomers to the anionic
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Questions

1–2 of 2 Questions  

  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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