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Merck

932698

Sigma-Aldrich

N4,N4,N4′,N4′-Tetra[(1,1′-biphenyl)-4-yl]-(1,1′-biphenyl)-4,4′-diamine

≥99% (HPLC)

Synonym(e):

N,N′-Tetra(4-biphenyl)benzidine, 4-Phenyl-n-(4-phenylphenyl)-n-[4-[4-(4-phenyl-n-(4-phenylphenyl)anilino)phenyl]phenyl]aniline, N,N,N′,N′-Tetrakis(4-biphenylyl)benzidine, N4,N4,N4′,N4′-Tetra(4-biphenylyl)-biphenyl-4,4′-diamine, BPBPA, [1,1′-Biphenyl]-4,4′-diamine, N4,N4,N4′,N4′-tetrakis([1,1′-biphenyl]-4-yl), [1,1′-Biphenyl]-4,4′-diamine, N4,N4,N4′,N4′-tetrakis([1,1′-biphenyl]-4-yl)

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About This Item

Empirische Formel (Hill-System):
C60H44N2
CAS-Nummer:
Molekulargewicht:
793.00
MDL-Nummer:
UNSPSC-Code:
12352116
NACRES:
NA.21
Assay:
≥99% (HPLC)
Qualität:
sublimed grade
Preise und Verfügbarkeit sind derzeit nicht verfügbar.

Qualität

sublimed grade

Qualitätsniveau

Assay

≥99% (HPLC)

SMILES String

N(c5ccc(cc5)c6ccc(cc6)N(c9ccc(cc9)c%10ccccc%10)c7ccc(cc7)c8ccccc8)(c3ccc(cc3)c4ccccc4)c1ccc(cc1)c2ccccc2

InChI

1S/C60H44N2/c1-5-13-45(14-6-1)49-21-33-55(34-22-49)61(56-35-23-50(24-36-56)46-15-7-2-8-16-46)59-41-29-53(30-42-59)54-31-43-60(44-32-54)62(57-37-25-51(26-38-57)47-17-9-3-10-18-47)58-39-27-52(28-40-58)48-19-11-4-12-20-48/h1-44H

InChIKey

WXAIEIRYBSKHDP-UHFFFAOYSA-N

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Anwendung

N4,N4,N4′,N4′-Tetra[(1,1′-biphenyl)-4-yl]-(1,1′-biphenyl)-4,4′-diamine, also known as BPBPA, is a Hole Transport, Electron Blocking Layer (HTL / EBL) material. BPBPA is popularly used in optoelectronic devices, such as high efficiency and long lifetime light-emitting diode devices (organic LEDs, OLEDs).
N4,N4,N4′,N4′-Tetra[(1,1′-biphenyl)-4-yl]-(1,1′-biphenyl)-4,4′-diamine is used as a hole transport material or as a host material in the emissive layer of organic light-emitting diodes (OLEDs) devices. Its semiconducting properties suits for R&D studies in organic field-effect transistors(OFETs) and thin-film transistors (TFTs).

Lagerklassenschlüssel

11 - Combustible Solids

WGK

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable


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Do Sik Kim et al.
ACS applied materials & interfaces, 12(17), 19737-19745 (2020-04-18)
Four electron transport type hosts withstanding the positive polaron stress were synthesized using the benzo[4,5]thieno[3,2-d]pyrimidine core to develop high triplet energy hosts. Four benzo[4,5]thieno[3,2-d]pyrimidine-derived hosts, 4-(9H-carbazol-9-yl)-2-(3-(triphenylsilyl)phenyl)benzo[4,5]thieno[3,2-d]pyrimidine (CzBTPmSi), 2,4-di(9H-carbazol-9-yl)benzo[4,5]thieno[3,2-d]pyrimidine (2CzBTP), 2-(9H-carbazol-9-yl)-4-(3-(triphenylsilyl)phenyl)benzo[4,5]thieno[3,2-d]pyrimidine (mSiBTPCz), and 2,4-bis(3-(triphenylsilyl)phenyl)benzo[4,5]thieno[3,2-d]pyrimidine (2mSiBTP), were designed to have either the
Efficient Wide-Bandgap Mixed-Cation and Mixed-Halide Perovskite Solar Cells by Vacuum Deposition
Gil-Escrig, Lidon, et al.
ACS Energy Letters, 6, 827-836 (2021)
A novel molecular design employing a backbone freezing linker for improved efficiency, sharpened emission and long lifetime in thermally activated delayed fluorescence emitters
Yu, Ji Gwang et al.
Journal of Materials Chemistry, 7, 2919-2926 (2019)
High triplet energy exciplex host derived from a CN modified carbazole based n-type host for improved efficiency and lifetime in blue phosphorescent organic light-emitting diodes
Shin, Su Kyeong, et al.
Journal of Materials Chemistry, 6, 10308-10314 (2018)
Superb lifetime of blue organic light-emitting diodes through engineering interface carrier blocking layers and adjusting electron leakage and an unusual efficiency variation at low electric field
Kim, Taekyung et al.
Journal of Materials Chemistry, 6, 8472-8478 (2018)

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