916129

1,10-Phenanthroline nickel (ll) dichloride

powder or crystals

• Synonym(e): phenNiCl₂
• Empirische Formel (Hill-System): C₁₂H₈Cl₂N₂Ni
• CAS-Nummer: 22980-76-3
• Molekulargewicht: 309.80
• MDL number: MFCD32706956
• UNSPSC Code: 12352200
• NACRES: NA.22
• Form: powder or crystals

Eigenschaften

• Produktname: 1,10-Phenanthroline nickel (ll) dichloride,
• form: powder or crystals
• Quality Segment: 100
• reaction suitability: reagent type: catalyst; reaction type: Cross Couplings
• greener alternative product characteristics: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Sustainability features
• mp: >300 °C
• SMILES string: [Ni].Cl.Cl.n1c2c3ncccc3ccc2ccc1
• InChI: 1S/C12H8N2.2ClH.Ni/c1-3-9-5-6-10-4-2-8-14-12(10)11(9)13-7-1;;;/h1-8H;2*1H;
• InChI key: CHVPLVVTLIMTJX-UHFFFAOYSA-N

Beschreibung

General description

We are committed to providing greener alternatives that adhere to the 12 Principles of Green Chemistry. This precatalyst serves as an efficient catalyst precursor that activates readily for selective transformations with minimal byproduct formation, thus aligns with Green Chemistry principle "Catalysis". Click here for more information.

Application

1,10-Phenanthroline nickel (ll) dichloride is a Ni precatalyst used for a variety of cross-coupling reactions, including N-alkylation of amides and arylation of alcohols.

Other Notes

Regioselective Single-Electron Tsuji-Trost Reaction of Allylic Alcohols: A Photoredox/Nickel Dual Catalytic Approach

Sicherheitshinweise

• Lagerklasse: 11 - Combustible Solids
• Was ist los?: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable