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66770

Methylendiamin -dihydrochlorid

≥98.0% (AT)

Synonym(e):

Diaminomethan -dihydrochlorid

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Größe/SKUVerfügbarkeitPreis
10 g
Warenkorb auf Verfügbarkeit prüfen
€ 273,00

Über diesen Artikel

Lineare Formel:
CH2(NH2)2 · 2HCl
CAS-Nummer:
Molekulargewicht:
118.99
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
260-602-6
Beilstein/REAXYS Number:
3664689
MDL number:
Assay:
≥98.0% (AT)
Form:
solid

€ 273,00


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Quality Segment

assay

≥98.0% (AT)

form

solid

functional group

amine

storage temp.

2-8°C

SMILES string

Cl.Cl.NCN

InChI

1S/CH6N2.2ClH/c2-1-3;;/h1-3H2;2*1H

InChI key

QCYJCJJCNRIMNG-UHFFFAOYSA-N

General description

Methylenediamine dihydrochloride, also known as Diaminomethane dihydrochloride is an organic compound that is often utilized as a reagent and slow ammonia-releasing agent during the synthesis of primary amides of peptides and amino acids from active esters.

Application

Methylenediamine dihydrochloride can be used as a reactant to synthesize:
  • Poly(methylene biguanides) via polycondensation reaction with sodium dicyanamide in the presence of 1-butanol.
  • Didodecanoylamides by reacting with (2S)-2-methyldodecanoyl chloride via acylation in the presence of sodium bicarbonate.
It can also be used as a hydrogen source in catalytic hydrogenation reactions.

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Dieser Artikel
784503896033220
description

≥98.0% (AT)

description

≥99.0% (AT)

description

purum, ≥98.0% (AT)

description

≥99.0% (AT)

assay

≥98.0% (AT)

assay

≥99.0% (AT)

assay

≥98.0% (AT)

assay

≥99.0% (AT)

Quality Level

200

Quality Level

100

Quality Level

200

Quality Level

200

form

solid

form

powder

form

-

form

powder

storage temp.

2-8°C

storage temp.

-

storage temp.

-

storage temp.

-

functional group

amine

functional group

-

functional group

amine

functional group

amine


Lagerklasse

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)



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Questions

1–3 of 3 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

  3. I am curious about where HCl is located and how it is bonded in the molecule.

    1 answer
    1. Both of the amino groups of the Methylenediamine are protonated (that is, as -NH3+ groups), with a chloride (Cl-) counterion associated with each of them. That is, it is best to think of the HCl as being dissociated, with H+ on the amine and Cl- as the counterion.

      Helpful?

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