496383

1,10-Phenanthrolin-5,6-dion

97%

• Synonym(e): Stahl phd oxidant, phd
• Empirische Formel (Hill-System): C₁₂H₆N₂O₂
• CAS-Nummer: 27318-90-7
• Molekulargewicht: 210.19
• MDL-Nummer: MFCD00014473
• UNSPSC-Code: 12352100
• PubChem Substanz-ID: 24873053
• NACRES: NA.22

Eigenschaften

• Assay: 97%
• mp (Schmelzpunkt): 260 °C (dec.) (lit.)
• SMILES String: O=C1C(=O)c2cccnc2-c3ncccc13
• InChI: 1S/C12H6N2O2/c15-11-7-3-1-5-13-9(7)10-8(12(11)16)4-2-6-14-10/h1-6H
• InChIKey: KCALAFIVPCAXJI-UHFFFAOYSA-N

Beschreibung

Allgemeine Beschreibung

1,10-Phenanthroline-5,6-dione (phendio) forms Cu(II) and Ag(I) phendio complexes, which show potent anti-fungal and anti-cancer activity. The modification of glassy carbon (GC) electrodes with phendio complexes of transition metals leads to the catalytic oxidation of NADH at low overpotential.

Anwendung

1,10-Phenanthroline-5,6-dione may be used in the preparation of homo- and heterometallic complexes with early transition metal ions.

A Bifunctional quinone oxidant which, when used in conjunction with Zn²⁺ catalysts, is used to affect the aerobic oxidation of secondary amines to a variety of value added motifs, including indoles.

Bioinspired Aerobic Oxidation of Secondary Amines and Nitrogen Heterocycles with a Bifunctional Quinone Catalyst

Sicherheitshinweise

• Piktogramme: GHS07
• Signalwort: Warning
• H-Sätze: H315,H319,H335
• P-Sätze: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Gefahreneinstufungen: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: dust mask type N95 (US), Eyeshields, Gloves