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Merck

316954

Sigma-Aldrich

Ammoniumperrhenat

≥99%

Synonym(e):

Metaperrhenic acid ammonium salt, Rhenium standard solution

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About This Item

Lineare Formel:
NH4ReO4
CAS-Nummer:
Molekulargewicht:
268.24
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12352302
PubChem Substanz-ID:
NACRES:
NA.23

Assay

≥99%

Form

powder or crystals

Eignung der Reaktion

reagent type: catalyst
core: rhenium

Dichte

3.97 g/mL at 25 °C (lit.)

SMILES String

N.O[Re](=O)(=O)=O

InChI

1S/H3N.H2O.3O.Re/h1H3;1H2;;;;/q;;;;;+1/p-1

InChIKey

XPSXHXWHJAIQJR-UHFFFAOYSA-M

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Allgemeine Beschreibung

Ammonium perrhenate is a white crystalline solid soluble in ethanol and water. It is a weak oxidizer and widely used as a Re precursor in nanomaterial synthesis and Re-based catalyst preparation.

Anwendung

Ammonium perrhenate used:
  • As a rhenium source to prepare Re nanoparticles for catalytic decomposition of ammonium perchlorate.
  • To synthesize ReS2 through a direct sulfidation reaction, for the fabrication of field effect transistors (FETs), digital logic devices, humidity sensors, and rechargeable supercapacitors.
  • As a precursor to prepare the heterogeneous catalysts for organic transformations.
  • An excellent precursor for the fabrication of ReOx/TiO2 recyclable solidcatalyst for deoxydehydration. For at least six runs in a row, the catalyst demonstrated catalyticactivity, selectivity, and stability without deactivation.

Lagerklassenschlüssel

13 - Non Combustible Solids

WGK

WGK 1

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Persönliche Schutzausrüstung

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


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The electronic, optical and chemical properties of two-dimensional transition metal dichalcogenides strongly depend on their three-dimensional atomic structure and crystal defects. Using Re-doped MoS2 as a model system, here we present scanning atomic electron tomography as a method to determine
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