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(R)-(−)-2-Phenylglycinmethylester -hydrochlorid
≥95%
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About This Item
Lineare Formel:
C6H5CH(NH2)CO2CH3·HCl
CAS-Nummer:
Molekulargewicht:
201.65
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12352200
eCl@ss:
32160406
PubChem Substanz-ID:
NACRES:
NA.22
Empfohlene Produkte
Assay
≥95%
Form
solid
Optische Aktivität
[α]20/D −118°, c = 1 in H2O
Eignung der Reaktion
reaction type: solution phase peptide synthesis
mp (Schmelzpunkt)
189-191 °C (lit.)
Anwendung(en)
peptide synthesis
SMILES String
Cl.COC(=O)[C@H](N)c1ccccc1
InChI
1S/C9H11NO2.ClH/c1-12-9(11)8(10)7-5-3-2-4-6-7;/h2-6,8H,10H2,1H3;1H/t8-;/m1./s1
InChIKey
DTHMTBUWTGVEFG-DDWIOCJRSA-N
Signalwort
Warning
H-Sätze
P-Sätze
Gefahreneinstufungen
Eye Irrit. 2
Lagerklassenschlüssel
11 - Combustible Solids
WGK
WGK 3
Flammpunkt (°F)
Not applicable
Flammpunkt (°C)
Not applicable
Persönliche Schutzausrüstung
dust mask type N95 (US), Eyeshields, Gloves
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A semi-random mutagenesis approach was followed to increase the performance of penicillin acylase PAS2 in the kinetically controlled synthesis of ampicillin from 6-aminopenicillanic acid (6-APA) and activated D-phenylglycine derivatives. We directed changes in amino acid residues to positions close to
M I Youshko et al.
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Kinetic regularities of the enzymatic acyl group transfer reactions have been studied using ampicillin synthesis catalyzed by E. coli penicillin acylase as an example. It was shown that ampicillin synthesis proceeds through the formation of an acylenzyme-nucleophile complex capable of
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