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Dokumente

283630

Sigma-Aldrich

Vinylferrocen

97%

Synonym(e):

Ethenylferrocene

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About This Item

Empirische Formel (Hill-System):
C12H12Fe
CAS-Nummer:
1271-51-8
Molekulargewicht:
212.07
EG-Nummer:
215-041-1
MDL-Nummer:
MFCD00001434
UNSPSC-Code:
12161600
PubChem Substanz-ID:
24857121
NACRES:
NA.22

Assay

97%

Form

solid

Eignung der Reaktion

core: iron
reagent type: catalyst

bp

80-85 °C/0.2 mmHg (lit.)

mp (Schmelzpunkt)

51-53 °C (lit.)

SMILES String

[Fe].[CH]1[CH][CH][CH][CH]1.C=C[C]2[CH][CH][CH][CH]2

InChI

1S/C7H7.C5H5.Fe/c1-2-7-5-3-4-6-7;1-2-4-5-3-1;/h2-6H,1H2;1-5H;

InChIKey

LCPVTGDQYVLJHU-UHFFFAOYSA-N

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Verwandte Kategorien

Anwendung

Synthesis of 2-aminomethylferrocenes from vinyl ferrocene and lithium amides.

Piktogramme

Flame
GHS02

Signalwort

Danger

H-Sätze

H228

P-Sätze

P210

Gefahreneinstufungen

Flam. Sol. 1

Lagerklassenschlüssel

4.1B - Flammable solid hazardous materials

WGK

WGK 3

Flammpunkt (°F)

143.6 °F - closed cup

Flammpunkt (°C)

62 °C - closed cup

Persönliche Schutzausrüstung

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

Analysenzertifikate (COA)

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(Dimethylaminomethyl)ferrocen ≥95%

Sigma-Aldrich

119342

(Dimethylaminomethyl)ferrocen

Ryoji Kurita et al.
Biosensors & bioelectronics, 20(3), 518-523 (2004-10-21)
This paper proposes a very simple procedure for preparing a biocompatible sensor based on a protein (bovine serum albumin, BSA), enzyme and vinylferrocene (VF) composite membrane modified electrode. The membrane was prepared simply by first casting vinylferrocene and then coating
Joachim Loup et al.
Angewandte Chemie (International ed. in English), 56(45), 14197-14201 (2017-09-19)
Highly enantioselective iron-catalyzed C-H alkylations by inner-sphere C-H activation were accomplished with ample scope. High levels of enantiocontrol proved viable through a novel ligand design that exploits a remote meta-substitution on N-heterocyclic carbenes within a facile ligand-to-ligand H-transfer C-H cleavage.
Ceren Kaçar et al.
Analytical and bioanalytical chemistry, 409(11), 2873-2883 (2017-02-12)
Highly sensitive L-lysine enzyme electrodes were constructed by using poly(vinylferrocene)-multiwalled carbon nanotubes-gelatine (PVF/MWCNTs-GEL) and poly(vinylferrocene)-multiwalled carbon nanotubes-gelatine-graphene (PVF/MWCNTs-GEL/GR) composites as sensing interfaces and their performances were evaluated. Lysine oxidase (LO) was immobilized onto the composite modified glassy carbon electrodes (GCE)
Takanori Tamaki et al.
The journal of physical chemistry. B, 111(34), 10312-10319 (2007-08-10)
We immobilized hydroquinone through a spacer to polymer grafted on carbon black and achieved a high-surface-area biofuel cell electrode. Quinone compounds are well-known to transfer electrons in the respiratory chain and have been considered prospective mediators in biofuel cells because
Kay L Robinson et al.
Analytical sciences : the international journal of the Japan Society for Analytical Chemistry, 24(3), 339-343 (2008-03-12)
Poly(vinylferrocene) (pVFc) homopolymer was synthesized by free radical polymerization, along with a series of pVFc-based copolymers containing either styrene, vinylanthracene or methylmethacrylate. This report details the electrochemical experiments conducted to examine the stability of the various pVFc based polymers, which
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