125512

Cyclopropylphenylketon

97%

• Synonym(e): Benzoylcyclopropan
• Lineare Formel: C₆H₅COC₃H₅
• CAS-Nummer: 3481-02-5
• Molekulargewicht: 146.19
• Beilstein: 1860145
• EG-Nummer: 222-458-2
• MDL-Nummer: MFCD00001294
• UNSPSC-Code: 12352100
• PubChem Substanz-ID: 24847671
• NACRES: NA.22

Eigenschaften

• Dampfdichte: 5 (vs air)
• Assay: 97%
• Brechungsindex: n20/D 1.553 (lit.)
• bp: 121-123 °C/15 mmHg (lit.)
• mp (Schmelzpunkt): 7-9 °C (lit.)
• Dichte: 1.058 g/mL at 25 °C (lit.)
• SMILES String: O=C(C1CC1)c2ccccc2
• InChI: 1S/C10H10O/c11-10(9-6-7-9)8-4-2-1-3-5-8/h1-5,9H,6-7H2
• InChIKey: PJRHFTYXYCVOSJ-UHFFFAOYSA-N

Beschreibung

Anwendung

Cyclopropyl phenyl ketone was used to prepare α-cyclopropylstyrene by the Wittig reaction in dimethyl sulfoxide. It was used as starting reagent during the (Z)-titanium enolate formation from cyclopropyl ketones via TiCl₄-n-Bu₄NI-induced ring opening reaction.

Sicherheitshinweise

• Lagerklassenschlüssel: 10 - Combustible liquids
• WGK: WGK 3
• Flammpunkt (°F): 194.0 °F - closed cup
• Flammpunkt (°C): 90 °C - closed cup
• Persönliche Schutzausrüstung: Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)