32201-M

Acetona

puriss. p.a., ACS reagent, reag. ISO, reag. Ph. Eur., ≥99.5% (GC)

• Fórmula lineal: CH₃COCH₃
• Número de CAS: 67-64-1
• Peso molecular: 58.08
• Beilstein: 635680
• Número CE: 200-662-2
• Número MDL: MFCD00008765
• Código UNSPSC: 12352115
• eCl@ss: 39021201
• ID de la sustancia en PubChem: 329754097
• NACRES: NA.02
• bp: 56 °C/760 mmHg (lit.)

Propiedades

• grado: ACS reagent; puriss. p.a.
• Agency: USP/NF; reag. ISO; reag. Ph. Eur.
• densidad de vapor: 2 (vs air)
• presión de vapor: 184 mmHg ( 20 °C)
• Ensayo: ≥99.5% (GC)
• Formulario: liquid
• lim. expl.: 13.2 %
• técnicas: UV/Vis spectroscopy: suitable
• impurezas: ≤0.0002% KMnO₄ red. matter (as O); ≤0.0002% benzene; ≤0.0008% free alkali (as NH₃); ≤0.001% aldehydes (as HCHO); ≤0.001% non-volatile matter; ≤0.0015% free acid (as CH₃COOH); ≤0.01% ethanol (GC); ≤0.05% 2-propanol; ≤0.05% methanol; ≤0.2% water (Karl Fischer)
• índice de refracción: n20/D 1.3580-1.3600; n20/D 1.359 (lit.)
• pH: 5-6 (20 °C, 395 g/L)
• bp: 56 °C/760 mmHg (lit.)
• mp: −94 °C (lit.)
• densidad: 0.791 g/mL at 25 °C (lit.)
• trazas de catión: Al: ≤0.5 ppm; B: ≤0.02 ppm; Ba: ≤0.1 ppm; Bi: ≤0.1 ppm; Ca: ≤0.5 ppm; Cd: ≤0.05 ppm; Co: ≤0.01 ppm; Cr: ≤0.02 ppm; Cu: ≤0.02 ppm; Fe: ≤0.1 ppm; K: ≤0.5 ppm; Li: ≤0.1 ppm; Mg: ≤0.1 ppm; Mn: ≤0.01 ppm; Mo: ≤0.1 ppm; Na: ≤0.5 ppm; Ni: ≤0.02 ppm; Pb: ≤0.02 ppm; Sn: ≤0.1 ppm; Sr: ≤0.1 ppm; Zn: ≤0.05 ppm
• cadena SMILES: CC(C)=O
• Formato: neat
• InChI: 1S/C3H6O/c1-3(2)4/h1-2H3
• Clave InChI: CSCPPACGZOOCGX-UHFFFAOYSA-N

Descripción

Descripción general

Mixtures of TiO₂ (P25) with rare earth oxides (La₂O₃ or Y₂O₃) calcined at 700°C or 650°C have been reported to efficiently photocatalyze oxidation of acetone.[1] Its aldol condensation in vapor-phase has been investigated over MgO promoted with alkali (Li, Na, K and Cs) or alkaline earth (Ca, Sr and Ba) metal ions.[2] It undergoes Aldol condensation in the presence of Mg-Al layered double hydroxides (LDH) as catalysts and Cl^- and/or CO₃^2- as compensating anions to afford diacetone alcohol and mesityl oxide.[3] Enantioselective Aldol condensation of acetone with various isatins in the presence of dipeptides (catalyst) has been described.[4]

Aplicación

La intensidad de luminiscencia de la acetona depende de los componentes de la disolución . La absorción de luz ultravioleta por la acetona tiene como consecuencia su fotólisis y la producción de radiales .

Acetone was used in the synthesis of Ga (Gallium)-DOTATATE (where DOTA=1,4,7,10-tetraazacyclo- dodecane -1,4,7,10-tetraacetic acid) chemicals.[5] It may be used in an assay for determination of ester groups in lipids by spectrophotometric methods.[6]

Información de seguridad

• Pictogramas: GHS02,GHS07
• Palabra de señalización: Danger
• Frases de peligro: H225,H319,H336
• Consejos de prudencia: P210 - P305 + P351 + P338
• Clasificaciones de peligro: Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
• Órganos de actuación: Central nervous system
• Riesgos supl.: EUH066
• Código de clase de almacenamiento: 3 - Flammable liquids
• Clase de riesgo para el agua (WGK): WGK 1
• Punto de inflamabilidad (°F): 1.4 °F - closed cup
• Punto de inflamabilidad (°C): -17.00 °C - closed cup