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133302

Sigma-Aldrich

Cyclohexyl isocyanide

98%

Sinónimos:

Isocyanocyclohexane

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About This Item

Fórmula lineal:
C6H11NC
Número de CAS:
931-53-3
Peso molecular:
109.17
Beilstein/REAXYS Number:
3662332
EC Number:
213-238-7
MDL number:
MFCD00003839
UNSPSC Code:
12352100
PubChem Substance ID:
24848099
NACRES:
NA.22

assay

98%

form

liquid

refractive index

n20/D 1.45 (lit.)

density

0.878 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

[C-]#[N+]C1CCCCC1

InChI

1S/C7H11N/c1-8-7-5-3-2-4-6-7/h7H,2-6H2

InChI key

XYZMOVWWVXBHDP-UHFFFAOYSA-N

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General description

Cyclohexyl isocyanide reacts with dimethyl acetylenedicarboxylate to give a mixture of cyclopenta[b]pyridine derivatives, azaspirononatriene derivative and the azabicyclononatriene. It reacts with dialkyl acetylenedicarboxylates to form 1:1 intermediate which on facile addition to 1-benzylisatin and tryptantrin yields highly functionalized novel unsaturated γ-spiroiminolactones.

application

  • Isocyanide in coordination chemistry: The study on mixed "2 + 1" tricarbonyl dithiocarbamate complexes highlights Cyclohexyl isocyanide′s role as an effective monodentate ligand, contributing to advancements in radiopharmaceutical applications using Re, Tc, and Re isotopes (Shegani et al., 2021).
  • Organic synthesis reagent in vascular treatments: The article discusses the use of Cyclohexyl isocyanide in modifying the endocannabinoid system, emphasizing its potential in developing treatments for conditions like hypertension through biochemical pathway modulation (Baranowska-Kuczko et al., 2021).
  • Chemical process optimization in dye decolorization: Cyclohexyl isocyanide plays a crucial role in the covalent immobilization of enzymes used for the decolorization of textile dyes, demonstrating its utility in environmental chemistry and industrial applications related to pollution control (Salami et al., 2018).
  • Application in nanocellulose modification: Demonstrates the versatility of Cyclohexyl isocyanide in nanotechnology by facilitating the covalent attachment of temperature-responsive polymers to cellulose nanofibrils, enhancing the material′s properties for use in smart textiles and responsive materials (Khine et al., 2018).

pictograms

Skull and crossbones
GHS06

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk_germany

WGK 3

flash_point_f

170.6 °F - closed cup

flash_point_c

77 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Certificados de análisis (COA)

Busque Certificados de análisis (COA) introduciendo el número de lote del producto. Los números de lote se encuentran en la etiqueta del producto después de las palabras «Lot» o «Batch»

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Sigma-Aldrich

188204

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1,1,3,3-Tetramethylbutyl isocyanide for synthesis

Sigma-Aldrich

8.18105

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Structure and Thermal Isomerization of the Adducts Formed in the Reaction of Cyclohexyl Isocyanide with Dimethyl Acetylenedicarboxylate1.
Junjappa H, et al.
The Journal of Organic Chemistry, 63(26), 9801-9805 (1998)
Synthesis of some novel ?-spiroiminolactones from reaction of cyclohexyl isocyanide and dialkyl acetylene dicarboxylates with 1-benzylisatin and tryptanthrine.
Azizian J, et al.
Synthetic Communications, 33(3), 387-391 (2003)
Sodam Kim et al.
Journal of controlled release : official journal of the Controlled Release Society, 322, 337-345 (2020-04-05)
Nuclear medicine is a routine but essential clinical option for diagnostic imaging and disease treatment. Encapsulating radioisotopes in injectable biodegradable hydrogels is ideal for localizing radiation sources to target tissues or organs to achieve long-term, low-dose radiotherapy. However, difficulties in
Ghasem Marandi
Combinatorial chemistry & high throughput screening, 21(4), 298-301 (2018-04-18)
The reaction of cyclohexylisocyanide and 2-aminopyridine-3- carboxylic acid in the presence of benzaldehyde derivatives in ethanol led to 3-(cyclohexylamino)-2- arylimidazo[1,2-a]pyridine-8-carboxylic acids in high yields. In a three component condensation reaction, isocyanide reacts with 2-aminopyridine-3-carboxylic acid and aromatic aldehydes without any
Marius Brehm et al.
Small (Weinheim an der Bergstrasse, Germany), 16(10), e1905971-e1905971 (2020-01-28)
Miniaturization and parallelization of combinatorial organic synthesis is important to accelerate the process of drug discovery while reducing the consumption of reagents and solvents. This work presents a miniaturized platform for on-chip solid-phase combinatorial library synthesis with UV-triggered on-chip cell

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