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Merck

416665

Sigma-Aldrich

tert-Butyl hydroperoxide solution

5.0-6.0 M in decane

Sinónimos:

1,1-Dimethylethyl hydroperoxide, 2-Hydroperoxy-2-methylpropane, TBHP

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25 ML
US$ 99,40
100 ML
US$ 294,00

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25 ML
US$ 99,40
100 ML
US$ 294,00

About This Item

Fórmula lineal:
(CH3)3COOH
Número de CAS:
Peso molecular:
90.12
Beilstein:
1098280
Número MDL:
Código UNSPSC:
12162002
ID de la sustancia en PubChem:
NACRES:
NA.23

US$ 99,40

PRECIOS SIN IMPUESTOS NACIONALES

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Solicitar un pedido a granel

Formulario

liquid

idoneidad de la reacción

reagent type: oxidant

concentración

5.0-6.0 M in decane
55.4-65.1% (Thiosulphate, titration)

impurezas

<4% water

índice de refracción

n20/D 1.402

densidad

0.808 g/mL at 25 °C

temp. de almacenamiento

2-8°C

cadena SMILES

CC(C)(C)OO

InChI

1S/C4H10O2/c1-4(2,3)6-5/h5H,1-3H3

Clave InChI

CIHOLLKRGTVIJN-UHFFFAOYSA-N

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Descripción general

tert-Butyl hydroperoxide is an organic peroxide, used in oxidation processes.

Aplicación

tert-Butyl hydroperoxide may be used in:
osmium catalyzed vicinal hydroxylation of olefins under alkaline conditions[1]
catalytic asymmetric oxidation of sulfides to sulfoxides using binaphthol as a chiral auxiliary[2]
oxidation of dibenzothiophenes[3]

Palabra de señalización

Danger

Clasificaciones de peligro

Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Aquatic Chronic 2 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 3 - Muta. 2 - Org. Perox. D - Skin Corr. 1C - Skin Sens. 1 - STOT SE 3

Órganos de actuación

Respiratory system

Código de clase de almacenamiento

5.2 - Organic peroxides and self-reacting hazardous materials

Clase de riesgo para el agua (WGK)

WGK 3

Punto de inflamabilidad (°F)

109.4 °F - closed cup

Punto de inflamabilidad (°C)

43 °C - closed cup

Equipo de protección personal

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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Certificados de análisis (COA)

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Visite la Librería de documentos

Oxidative desulfurization of fuel oil: Part I. Oxidation of dibenzothiophenes using tert-butyl hydroperoxide.
Wang D, et al.
Applied Catalysis A: General, 91-99 (2003)
Osmium catalyzed vicinal hydroxylation of olefins by tert-butyl hydroperoxide under alkaline conditions.
Sharpless KB and Akashi K
Journal of the American Chemical Society, 98(7), 1986-1987 (1976)
Catalytic asymmetric oxidation of sulfides to sulfoxides with tert-butyl hydroperoxide using binaphthol as a chiral auxiliary
Komatsu N, et al.
The Journal of Organic Chemistry, 58(17), 4529-4533 (1993)
Grace McCambridge et al.
Biomolecules, 9(2) (2019-03-03)
Circulating fatty acids (FAs) increase with obesity and can drive mitochondrial damage and inflammation. Nicotinamide nucleotide transhydrogenase (NNT) is a mitochondrial protein that positively regulates nicotinamide adenine dinucleotide phosphate (NADPH), a key mediator of energy transduction and redox homeostasis. The
Aldrichimica Acta, 12, 63-63 (1979)

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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