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339350

Sigma-Aldrich

Nickel(II) chloride

98%

Synonyme(s) :

Nickel dichloride, Nickel(2+) chloride, Nickelous chloride

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About This Item

Formule linéaire :
NiCl2
Numéro CAS:
Poids moléculaire :
129.60
Numéro CE :
Numéro MDL:
Code UNSPSC :
12352302
ID de substance PubChem :
Nomenclature NACRES :
NA.23
Essai:
98%
Forme:
powder

Niveau de qualité

Essai

98%

Forme

powder

Pertinence de la réaction

reagent type: catalyst
core: nickel

Densité

3.55 g/mL at 25 °C (lit.)

Application(s)

battery manufacturing

Chaîne SMILES 

Cl[Ni]Cl

InChI

1S/2ClH.Ni/h2*1H;/q;;+2/p-2

Clé InChI

QMMRZOWCJAIUJA-UHFFFAOYSA-L

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Description générale

Nickel(II) chloride 98% comes in a powder form and is a highly useful inorganic compound with a broad range of applications across various industries. Its relatively high purity makes it suitable for both industrial and laboratory settings. It is widely used in catalysis, electroplating, battery manufacturing, chemical synthesis, material science, dye and pigment production, and laboratory research.

Application

Nickel(II) chloride is utilized in the manufacturing of nickel-cadmium batteries, serving as a crucial component in the electrochemical reactions occurring within these rechargeable batteries. It is also suitable for use in theR&D activities of nickel-metal hydride (NiMH) batteries, which are used in various portable electronic devices and hybrid vehicles. In an experimet it has been found that Ni-NiCl2 composite cathode increased the output energy by ∼47% when the thermal batteries were used in weapons (working voltage >25 V), with a power density of up to 11.4 kW/kg. It is suitable as a catalyst or reagent in various organic synthesis reactions, such as cross-coupling reactions, amination, and cycloaddition reactions. In an experiment, it has been established that a wide variety of acyclic and cyclic dithioacetals can be prepared chemoselectively from the corresponding aldehydes by employing a catalytic amount of nickel(II) chloride in dry CH2Cl2–MeOH (5:1) at room temperature in good yields.

Caractéristiques et avantages

Some of the major advantages of this product is as a catalyst its high chemoselectivity, ease of operation, high yields, and also compatibility with other protecting groups. The compound′s capacity to aid in advanced material synthesis and promote environmental sustainability further highlights its value across various fields.
The vapor-phase co-reductions with other metal halides such as aluminum chloride (cat. no. 449598) by hydrogen results in finely divided intermetallics with applications as structural materials or compounds with useful thermoelectric, magnetic, and oxidation-resistance properties. Used in the synthesis of semiconducting metal-containing polymers in which the polypyrrole backbone has a conformational energy minimum and is nearly planar.
The vapor-phase co-reductions with other metal halides such as aluminum chloride (cat. no. 449598) by hydrogen results in finely divided intermetallics with applications as structural materials or compounds with useful thermoelectric, magnetic, and oxidation-resistance properties. Used in the synthesis of semiconducting metal-containing polymers in which the polypyrrole backbone has a conformational energy minimum and is nearly planar.

Pictogrammes

Skull and crossbonesHealth hazardEnvironment

Mention d'avertissement

Danger

Classification des risques

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1A Inhalation - Muta. 2 - Repr. 1B - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 1 Inhalation

Organes cibles

Lungs

Code de la classe de stockage

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable

Équipement de protection individuelle

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Consulter la Bibliothèque de documents

The radiochemistry of nickel, 3051 (1961)
Yifan Chen et al.
Nature communications, 11(1), 5334-5334 (2020-10-23)
Current techniques of patterned material deposition require separate steps for patterning and material deposition. The complexity and harsh working conditions post serious limitations for fabrication. Here, we introduce a single-step and easy-to-adapt method that can deposit materials in-situ. Its methodology
Nickel (II) Chloride
Luh T, et al.
Encyclopedia of Reagents for Organic Synthesis, Second Edition, 1-9 (2001)
The sodium/nickel chloride (ZEBRA) battery
Sudworth JL
Journal of Power Sources, 100(1-2), 149-163 (2001)
Polysulfone Nanocomposite Membranes with improved hydrophilicity
Phelane L, et al.
Electrochimica Acta, 128, 326-335 (2014)

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