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Merck
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重要文件

T6381

Supelco

N,O-双(三甲基硅)三氟乙酰胺(含三甲基氯硅烷)

N,O-Bis(trimethylsilyl)trifluoroacetamide with trimethylchlorosilane
1 of 1 reviewers received a sample product or took part in a promotion

with 1% trimethylchlorosilane, for GC derivatization, LiChropur

同義詞:

BSTFA + TMCS

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About This Item

線性公式:
CF3C[=NSi(CH3)3]OSi(CH3)3
CAS號碼:
分子量::
257.40
Beilstein:
2050024
MDL號碼:
分類程式碼代碼:
12000000
PubChem物質ID:
NACRES:
NA.22
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等級

derivatization grade ((GC derivatization))
for GC derivatization

品質等級

品質

LiChropur
with 1% trimethylchlorosilane

包含

1% trimethylchlorosilane as additive

反應適用性

reagent type: derivatization reagent
reaction type: Silylations

技術

gas chromatography (GC): suitable

顏色

hazy clear to colorless

折射率

n20/D 1.384 (lit.)

bp

45-50 °C/14 mmHg (lit.)

溶解度

hexane: miscible 100 mg/mL

密度

0.97 g/mL (lit.)

儲存溫度

2-8°C

SMILES 字串

C[Si](C)(C)O\C(=N\[Si](C)(C)C)C(F)(F)F

InChI

1S/C8H18F3NOSi2/c1-14(2,3)12-7(8(9,10)11)13-15(4,5)6/h1-6H3/b12-7+

InChI 密鑰

XCOBLONWWXQEBS-KPKJPENVSA-N

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一般說明

含有三甲基氯硅烷的N,O-双(三甲基甲硅烷基)三氟乙酰胺是一种甲硅烷基化试剂,通常用于雌激素类固醇激素的鉴定和定量。[1]

應用

BSTFA+TMCS已被用作衍生化试剂,用于通过GC-MS测定天然和合成的雌激素类固醇。[1]

包裝

密封安瓿包装,包含1 ml。固体克规格的样品包装于螺旋盖瓶中。
透明的硼硅酸盐玻璃,高耐水解性(I 型)

其他說明

甲硅烷基团的位置尚未明确确定。表示为 N,NN,O 两种。

法律資訊

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

相關產品

象形圖

FlameExclamation mark

訊號詞

Danger

危險聲明

危險分類

Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

44.1 °F - closed cup

閃點(°C)

6.7 °C - closed cup

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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Analytica Chimica Acta, 554.1, 190-196 (2005)
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Propolis is a sticky material mixed by honeybees to utilize it in protecting their hives from infection by bacteria and fungi. The therapeutic properties of propolis are due to its chemical composition with bio-active compounds; therefore, researchers are interested in
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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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