跳轉至內容
Merck
全部照片(1)

重要文件

69479

Supelco

N-甲基-N-(三甲基硅烷基)三氟乙酰胺

N-Methyl-N-(trimethylsilyl)trifluoroacetamide

for GC derivatization, LiChropur, ≥98.5%

同義詞:

N-三甲基硅基-N-甲基三氟乙酰胺, MSTFA

登入查看組織和合約定價


About This Item

線性公式:
CF3CON(CH3)Si(CH3)3
CAS號碼:
分子量::
199.25
Beilstein:
1941550
EC號碼:
MDL號碼:
分類程式碼代碼:
12000000
PubChem物質ID:
NACRES:
NA.22
暫時無法取得訂價和供貨情況

等級

for GC derivatization

品質等級

蒸汽密度

>1 (vs air)

蒸汽壓力

8.8 mmHg ( 27 °C)

化驗

≥98.5% (GC)
≥98.5%

形狀

liquid

品質

LiChropur

反應適用性

reagent type: derivatization reagent
reaction type: Silylations

技術

gas chromatography (GC): suitable

折射率

n20/D 1.38 (lit.)
n20/D 1.380

bp

130-132 °C (lit.)

密度

1.075 g/mL at 25 °C (lit.)

儲存溫度

2-8°C

SMILES 字串

CN(C(=O)C(F)(F)F)[Si](C)(C)C

InChI

1S/C6H12F3NOSi/c1-10(12(2,3)4)5(11)6(7,8)9/h1-4H3

InChI 密鑰

MSPCIZMDDUQPGJ-UHFFFAOYSA-N

尋找類似的產品? 前往 產品比較指南

一般說明

N-甲基-N-(三甲基甲硅烷基)三氟乙酰胺(MSTFA)是一种甲硅烷基化试剂。[1]

應用

更多信息请参见产品信息
MSTFA可用于甲硅烷基化过程,以使用GC-MS对类固醇激素17α-乙炔雌二醇(EE2)和雌酮进行测定。MSTFA与三甲基甲硅烷基氯(TMCS)一起在乙酸乙酯、乙腈和二氯甲烷溶剂中可导致三甲基甲硅烷基(TMS)和丁基二甲基甲硅烷基(TBS)衍生物的形成。[1]
适用于胺,氨基酸,羧基,羟胺,吲哚烷基胺,正亚硝基氨基酸,核苷,酚烷基胺,5-羟色胺和色胺的衍生化。

其他說明

用于N-乙酰基-N,三氟乙酰基,三甲基甲硅烷基,N-三甲基甲硅烷基-N-三氟乙酰基和O-三甲基甲硅烷基(TMS)的试剂
高效硅烷化试剂[2][3][4][5]

法律資訊

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

相關產品

象形圖

FlameExclamation mark

訊號詞

Warning

危險分類

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

77.0 °F - closed cup

閃點(°C)

25 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


從最近期的版本中選擇一個:

分析證明 (COA)

Lot/Batch Number

未看到正確版本?

如果您需要一個特定的版本,您可以透過批號來尋找特定憑證。

已經擁有該產品?

您可以在文件庫中找到最近購買的產品相關文件。

存取文件庫

J. Heberle et al.
Silylating Agents, 2nd ed. (1995)
Journal of Chromatography A, 115, 591-591 (1975)
M. Donike
Chromatographia, 9, 440-440 (1976)
Hieng-Ming Ting et al.
Frontiers in plant science, 11, 257-257 (2020-03-27)
Glucosinolates are defense-related secondary metabolites found in Brassicaceae. When Brassicaceae come under attack, glucosinolates are hydrolyzed into different forms of glucosinolate hydrolysis products (GHPs). Among the GHPs, isothiocyanates are the most comprehensively characterized defensive compounds, whereas the functional study of
M Donike et al.
Journal of chromatography, 134(2), 385-395 (1977-04-11)
The 1N-TMS-omegan-TFA-derivatives of indolalkylamines are suitable for estimation by combined gas chromatography and mass spectrometry for two reasons, viz. (1) Under electron impact charge stabilisation at the indole nucleus is favoured, so structure-specific ions form the base peak. For unsubstituted

文章

Development and validation of a fatty acid methyl esterification method, using methanolic HCl reagent, for FAME analysis by GC of vegetable oils and fats.

Results of a study involving the ability few Fluka silylating reagents to form GC-MS-compatible trimethylsilylmethyl derivatives of NSAIDs

條款

Example displays how MSTFA/MSTFA-d9 derivatization of amphetamine provides valuable information in mass spectra and chromatograms using SLB-5ms GC column.

範例顯示使用 SLB-5ms GC 色譜柱對苯丙胺進行 MSTFA/MSTFA-d9 衍生化如何在質譜和色譜圖中提供有價值的資訊。

Questions

1–3 of 3 Questions  
  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Helpful?

  3. What is the packaging of the product N-Methyl-N-(trimethylsilyl)trifluoroacetamide, code: 69479-10X1ML, bottle, ampoule, blister or other??

    1 answer
    1. The 1ML size is packaged in a 5mL amber glass vial with a Schwarz-type septum cap. The vials are then placed in a 10-place overpack box with dividers to protect each vial. Please see the image below of this cap type.

      Helpful?

Reviews

Active Filters

  1. 1 Ratings-Only Review

我們的科學家團隊在所有研究領域都有豐富的經驗,包括生命科學、材料科學、化學合成、色譜、分析等.

聯絡技術服務