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重要文件

32304

Sigma-Aldrich

草酸铵 一水合物

puriss. p.a., ACS reagent, reag. ISO, reag. Ph. Eur., 99.5-101.0%

同義詞:

草酸 二铵盐

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About This Item

線性公式:
(NH4)2C2O4 · H2O
CAS號碼:
分子量::
142.11
Beilstein:
3759830
EC號碼:
MDL號碼:
分類程式碼代碼:
12352302
PubChem物質ID:
NACRES:
NA.21
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等級

ACS reagent
puriss. p.a.

agency

USP/NF
reag. ISO
reag. Ph. Eur.

蒸汽壓力

<0.1 hPa ( 20 °C)

化驗

99.5-101.0%

形狀

crystalline

雜質

≤0.005% in water insoluble matters

燃燒殘留物

≤0.02% (as SO4)

pH值

6-7 (20 °C, 2.5%)

mp

133 °C (dec.) (lit.)

負離子痕跡

chloride (Cl-): ≤5 mg/kg
nitrate (NO3-): ≤5 mg/kg
sulfate (SO42-): ≤20 mg/kg

正離子痕跡

Ca: ≤10 mg/kg
Cd: ≤5 mg/kg
Cu: ≤5 mg/kg
Fe: ≤2 mg/kg
K: ≤10 mg/kg
Mg: ≤10 mg/kg
Na: ≤10 mg/kg
Pb: ≤5 mg/kg
Zn: ≤5 mg/kg

SMILES 字串

OC(C(O)=O)=O.N.O.N

InChI

1S/C2H2O4.2H3N.H2O/c3-1(4)2(5)6;;;/h(H,3,4)(H,5,6);2*1H3;1H2

InChI 密鑰

MSMNVXKYCPHLLN-UHFFFAOYSA-N

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相關類別

一般說明

Ammonium oxalate monohydrate is the diammonium salt of oxalic acid. Its refined crystal structure has been investigated by three-dimensional diffraction studies.[1] Influence of bivalent [Mn(II), Co(II), Ni(II)] and trivalent cations [Fe(III), Cr(III)] impurities on the growth rates of ammonium oxalate monohydrate crystals has been described.[2] Its space group and unit cell parameters have been analyzed by neutron diffraction studies.[3] Its IR spectra has been compared with that of isolated coal-solubilizing agent (CSA).[4]

應用

Ammonium oxalate monohydrate may be used to prepare an electrochemiluminescence (ECL) solution containing 1mM tris(2,2-bipyridyl)ruthenium(II) (Ru(bpy)32+) and 0.2mM ammonium oxalate monohydrate in a 0.1M ammonium acetate buffer at pH 5.0.[5]

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Acute Tox. 4 Oral - Eye Irrit. 2

儲存類別代碼

13 - Non Combustible Solids

水污染物質分類(WGK)

WGK 1

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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Neutron diffraction study of ammonium oxalate monohydrate,(NH4)2C2O4.H2O.
Padmanabhan VM, et al.
Acta Crystallographica, 18(3), 567-568 (1965)
Effect of impurities on metastable zone width for the growth of ammonium oxalate monohydrate crystals from aqueous solutions.
Sangwal K and Mielniczek-Brzoska E.
Journal of Crystal Growth, 267(3), 662-675 (2004)
M S Cohen et al.
Applied and environmental microbiology, 56(11), 3285-3291 (1990-11-01)
Low-ranked coals were dissolved by using cell extracts derived from liquid cultures of Trametes versicolor. The coal-solubilizing agent (CSA) was separated from the broth components by a multistep isolation procedure including reverse-phase high-pressure liquid chromatography, size exclusion chromatography, ethanol fractionation
Ammonium oxalate monohydrate: structure refinement at 30K.
Robertson JH.
Acta Crystallographica, 18(3), 410-417 (1965)
Electrochemiluminescence as a tool for microscopy at the nanoscale.
Lee A, et al.
Proceedings of SPIE, 13, 13-20 (2004)

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