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251755

Sigma-Aldrich

四氧化锇 溶液

4 wt. % in H2O

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About This Item

線性公式:
OsO4
CAS號碼:
分子量::
254.23
MDL號碼:
分類程式碼代碼:
12352303
PubChem物質ID:
NACRES:
NA.21
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等級

for analytical purposes

蒸汽壓力

1.23 psi ( 20 °C)
3.55 psi ( 55 °C)

形狀

liquid

反應適用性

reagent type: oxidant

濃度

3.5-4.5% (OsO4)
4 wt. % in H2O

密度

1.0 g/mL at 20 °C
1.04 g/mL at 25 °C

儲存溫度

2-8°C

SMILES 字串

O=[Os](=O)(=O)=O

InChI

1S/4O.Os

InChI 密鑰

VUVGYHUDAICLFK-UHFFFAOYSA-N

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一般說明

OsO4(4wt%,溶于 H2O)广泛应用于有机合成,特别是羟基化反应。此外,它还参与烯烃的氧化裂解。

應用


  • 大型生物样品的原位X射线辅助电子显微镜染色。:研究探讨了四氧化锇溶液在X射线辅助电子显微镜染色中的应用,增强了大型生物样品的可视化(Ströh et al., 2022)。

  • 电子显微镜在蝾螈白细胞细胞化学过氧化物酶反应中的应用。:在电子显微镜分析法中使用四氧化锇溶液增强了蝾螈白细胞中过氧化物酶反应的细胞化学分析,提供了清晰详细的图像(MITSUI, 1960)。


象形圖

Skull and crossbonesCorrosion

訊號詞

Danger

危險分類

Acute Tox. 2 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Irrit. 2

儲存類別代碼

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

水污染物質分類(WGK)

WGK 1

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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分析證明 (COA)

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存取文件庫

Asymmetric induction in the reaction of osmium tetroxide with olefins.
Hentges SG and Barry Sharpless K.
Journal of the American Chemical Society, 102(12), 4263-4265 (1980)
On stereochemistry of osmium tetroxide oxidation of allylic alcohol systems: empirical rule.
Cha JK, et al.
Tetrahedron Letters, 24(37), 3943-3946 (1983)
Kinetics of Oxidation of Some Fluoroquinolones by Hexacyanoferrate (III) in Alkaline Medium.
Diab N, et al.
International Journal of Chemistry (Canadian Center of Science and Education), 34(2), 1388-1388 (2013)
F Wyss et al.
Veterinary pathology, 52(6), 1235-1242 (2015-01-27)
Pododermatitis is frequent in captive flamingos worldwide, but little is known about the associated histopathologic lesions. Involvement of a papillomavirus or herpesvirus has been suspected. Histopathologic evaluation and viral assessment of biopsies from 19 live and 10 dead captive greater
Yukihiko Sugita et al.
The Journal of general virology, 92(Pt 11), 2485-2493 (2011-07-29)
Negatively stained influenza virions sometimes show irregular morphology and are often referred to as pleomorphic. However, this irregular morphology has not been visualized when ultrathin-section transmission and scanning electron microscopies are used. This study focused on the effects of ultracentrifugation

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    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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