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92330

Sigma-Aldrich

硼酸三甲酯

purum, ≥99.0% (GC)

同義詞:

三甲氧基硼烷, 硼酸甲酯

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About This Item

線性公式:
B(OCH3)3
CAS號碼:
分子量::
103.91
Beilstein:
1697939
EC號碼:
MDL號碼:
分類程式碼代碼:
12352103
PubChem物質ID:
NACRES:
NA.22

蒸汽密度

3.59 (vs air)

品質等級

等級

purum

化驗

≥99.0% (GC)

形狀

liquid

折射率

n20/D 1.346 (lit.)
n20/D 1.358

bp

68-69 °C (lit.)

mp

−34 °C (lit.)

密度

0.932 g/mL at 20 °C (lit.)

SMILES 字串

COB(OC)OC

InChI

1S/C3H9BO3/c1-5-4(6-2)7-3/h1-3H3

InChI 密鑰

WRECIMRULFAWHA-UHFFFAOYSA-N

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應用

硼酸三甲酯(TMB)可用于:
  • 合成以三苯胺为核、外围接四苯乙烯单元的发光分子。
  • 合成硼烷氨和三烷基胺硼烷。
  • 在硼烷二甲硫醚的存在下还原羧酸。
  • 交联磷酸盐复合物。
  • 作为化学气相沉积法合成氮化硼纳米管的硼源。

訊號詞

Danger

危險分類

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Irrit. 2 - Flam. Liq. 2 - Repr. 1B - STOT SE 1

標靶器官

Eyes

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 1

閃點(°F)

12.2 °F - (own results)

閃點(°C)

-11 °C - (own results)

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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分析證明 (COA)

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Organic synthesis using borane-methyl sulfide. II. Reduction of aromatic carboxylic acids in the presence of trimethyl borate.
Lane CF, et al.
The Journal of Organic Chemistry, 39(20), 3052-3054 (1974)
Thermal-heating CVD synthesis of BN nanotubes from trimethyl borate and nitrogen gas.
Lin FH, et al.
Materials Chemistry and Physics, 107(1), 115-121 (2008)
Changing the Behavior of Chromophores from Aggregation?Caused Quenching to Aggregation?Induced Emission: Development of Highly Efficient Light Emitters in the Solid State.
Yuan W Z, et al.
Advanced Materials, 22(19), 2159-2163 (2010)
One-Pot Synthesis of Ammonia-Borane and Trialkylamine-Boranes from Trimethyl Borate.
Veeraraghavan RP, et al.
Organic Letters, 14(24), 6119-6121 (2012)
Scott Gronert et al.
Journal of the American Society for Mass Spectrometry, 13(9), 1088-1098 (2002-09-27)
Using a quadrupole ion trap mass spectrometer, trimethyl borate was allowed to react with dihydrogen phosphate, deprotonated O-phosphoserine, and a set of hydrogen bonded complexes involving dihydrogen phosphate and neutral acids (phosphoric acid, acetic acid, serine, and O-phosphoserine). The reactions

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