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72240

Sigma-Aldrich

铝镍合金

purum, 50% Al basis, 50% Ni basis

同義詞:

Raney® 镍合金, 镍铝合金

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About This Item

CAS號碼:
MDL號碼:
分類程式碼代碼:
12161600
PubChem物質ID:
NACRES:
NA.22
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品質等級

等級

purum

形狀

powder

成份

Al, 50%
Ni, 50%

反應適用性

core: nickel
reagent type: catalyst

SMILES 字串

[Al].[Ni]

InChI

1S/Al.Ni

InChI 密鑰

NPXOKRUENSOPAO-UHFFFAOYSA-N

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應用

铝镍合金可用于:
  • 将腈类、硝基和肟类化合物还原为一级胺。[1]
  • 将羰基化合物转化为烃类物质。[2]
  • 作为还原剂将Ar-X衍生物转化为Ar-H化合物。[1]
  • 合成雷尼镍催化剂,用作烷化剂。[3][4]
  • 通过碱浸法合成非自燃镍催化剂。[5]
  • 合成合金的骨架镍催化剂。[6]

法律資訊

Raney is a registered trademark of W.R. Grace & Co.-Conn.

取代透過

產品號碼
描述
訂價

訊號詞

Danger

危險分類

Carc. 2 - Flam. Sol. 1 - Skin Sens. 1 - Water-react 2

儲存類別代碼

4.3 - Hazardous materials which set free flammable gases upon contact with water

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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分析證明 (COA)

Lot/Batch Number

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存取文件庫

Highly selective hydrogenation of C?C double bond in unsaturated carbonyl compounds over NiC catalyst.
Mahata N, et al.
Chemical Engineering Journal, 188(4), 155-159 (2012)
An environmentally benign and catalytically efficient non-pyrophoric Ni catalyst for aqueous-phase reforming of ethylene glycol.
Zhu LJ, et al.
Green Chemistry, 10(12), 1323-1330 (2008)
Steam reforming of ethanol over skeletal Ni-based catalysts: A temperature programmed desorption and kinetic study
Zhang C, et al.
AIChE Journal, 60(2), 635-644 (2014)
Nickel-aluminum alloy as a reducing agent.
Keefer LK and Lunn G
Chemical Reviews, 89(3), 459-502 (1989)
Reinvestigating Raney nickel mediated selective alkylation of amines with alcohols via hydrogen autotransfer methodology.
Mehta A, et al.
Applied Catalysis A: General, 478(4), 241-251 (2014)

文章

An article concerning self-propagating reactions induced by mechanical alloying, presented by Sigma-Aldrich.com.

機械合金化是一種影響合金化學反應的 「粗暴 」方法。反應物粉末與數個球的混合物被放置在高能量球磨機的研磨罐中,例如震動式研磨機或行星式研磨機。

鎳複合物可催化各種合成反應,如氧化加成、C-H 活化和交叉耦合。

Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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