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重要文件

510033

Sigma-Aldrich

Raney®-镍

W.R. Grace and Co. Raney® 2400, slurry, in H2O, active catalyst

同義詞:

海绵镍

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About This Item

線性公式:
AlNi
CAS號碼:
MDL號碼:
分類程式碼代碼:
12161600
PubChem物質ID:
NACRES:
NA.22
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品質等級

形狀

slurry

反應適用性

core: nickel
reagent type: catalyst

製造商/商標名

W.R. Grace and Co. Raney® 2400

濃度

in H2O

SMILES 字串

[Al].[Ni]

InChI

1S/Al.Ni

InChI 密鑰

NPXOKRUENSOPAO-UHFFFAOYSA-N

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應用

Used as reducing agent for hydrogenation of organic compounds, e.g. hydrogenation of nitriles to amines, reduction of aromatic groups to the corresponding saturated compounds, hydrogenation reaction of β-keto esters, rreduction of amination, and also used as 3-alkylation of oxindole with alcohol, and Ullman-type cross coupling, and dehalogenation reactions.

法律資訊

Raney is a registered trademark of W.R. Grace & Co.-Conn.

訊號詞

Danger

危險分類

Carc. 2 - Pyr. Liq. 1 - Skin Sens. 1 - STOT RE 1

儲存類別代碼

4.2 - Pyrophoric and self-heating hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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文章

鎳複合物可催化各種合成反應,如氧化加成、C-H 活化和交叉耦合。

Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.

Questions

1–7 of 7 Questions  
  1. Is it in a septum sealed bottle or open to bottle? Basically I am asking if I need a needle or would just a flat tip work? All work will be done in N2 glove bag.

    1 answer
    1. This product is packaged under nitrogen in HDPE bottles with screw caps. This item is prepared as a slurry of Raney 2400 Nickel in water as the material is unstable in the dry form. Handling in a glove bag or box is not required, but may minimize the possibility of evaporation or drying.

      Helpful?

  2. What is the bulk density of Raney® 2400 Nickel, Product 510033?

    1 answer
    1. According to the manufacturer, the bulk density is about 15-17 lbs/gallon.

      Helpful?

  3. What is the composition of the Raney® 2400 Nickel, Product 510033?

    1 answer
    1. According to the manufacturer, the Raney® 2400 Nickel contains about >81.0% nickel, 6.0-13.0% aluminum, 2.0-3.0% iron, and 2.0-3.0% chromium.

      Helpful?

  4. What is the Department of Transportation shipping information for this product?

    1 answer
    1. Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.

      Helpful?

  5. In what applications can Raney® 2400 Nickel, Product 510033, be used?

    1 answer
    1. It is typically used as a hydrogenation catalyst for nitrile, olefin and nitro group reductions.

      Helpful?

  6. What is the particle size of the Raney® 2400 Nickel, Product 510033, solid that is used in the slurry?

    1 answer
    1. The particle size is expected to be between 25-55 microns.

      Helpful?

  7. What is the pH of the Raney® 2400 Nickel, Product 510033?

    1 answer
    1. The pH of the water layer is expected to be in the range of 8.5-12.5.

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