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P29006

Sigma-Aldrich

苯膦酸

98%

同義詞:

Benzene phosphonic acid

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About This Item

線性公式:
C6H5P(O)(OH)2
CAS號碼:
1571-33-1
分子量：:
158.09
Beilstein:
2245168
EC號碼:
216-388-1
MDL號碼:
MFCD00002136
分類程式碼代碼:
12352300
PubChem物質ID:
24898371
NACRES:
NA.23
暫時無法取得訂價和供貨情況

品質等級

200

化驗

98%

形狀

crystals

mp

162-164 °C (lit.)

SMILES 字串

OP(O)(=O)c1ccccc1

InChI

1S/C6H7O3P/c7-10(8,9)6-4-2-1-3-5-6/h1-5H,(H2,7,8,9)

InChI 密鑰

QLZHNIAADXEJJP-UHFFFAOYSA-N

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相關類別

應用

与 Noyori 催化剂配合使用，用于将硫化物氧化为砜类的添加剂。

Noyori 氧化（二水合钨酸钠、过氧化氢、甲基三正辛基硫酸氢铵、磷酸）
苯基膦酸的自组装单分子膜 (SAMs) 可用于制备有机半导体与透明导电氧化物之间的界面。[1]酸可用于使二氧化钛颗粒功能化。[2]与 Noyor® 催化剂配合使用，用于硫化物绿色氧化为砜。

象形圖

CorrosionExclamation mark
GHS05,GHS07

訊號詞

Danger

危險聲明

H302,H314

危險分類

Acute Tox. 4 Oral - Skin Corr. 1B

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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分析證明 (COA)

Lot/Batch Number
MKCM8316
MKCM0595
MKCJ5393
MKBD2147V
MKBT8259V

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Important reaction parameters in the synthesis of phenylphosphonic acid functionalized titania particles by reactive milling.
Betke A and Kickelbick G
New. J. Chem., 38(3), 1264-1270 (2014)
T Q Duong et al.
Magnetic resonance in medicine, 45(5), 801-810 (2001-04-27)
The apparent diffusion coefficients (ADCs) of a series of markers concentrated in the extracellular space of normal rat brain were measured to evaluate, by inference, the ADC of water in the extracellular space. The markers (mannitol, phenylphosphonate, and polyethylene glycols)
Justin L Ford et al.
Helicobacter, 12(6), 609-615 (2007-11-16)
Helicobacter pylori can utilize phenylphosphonate as a sole source of phosphorus, and it is able to transport the phosphonate N-phosphonoacetyl-L-aspartate. However, H. pylori does not have any genes homologous to those of the known pathways for phosphonate degradation in bacteria
Christel Gervais et al.
Magnetic resonance in chemistry : MRC, 42(5), 445-452 (2004-04-20)
1H, 13C, 17O and 31P NMR parameters, including chemical shift tensors and quadrupolar parameters for 17O, were calculated for phenylphosphonic acid, C6H5PO(OH)2, under periodic boundary conditions. The results are in very good agreement with experimental data and permit the unambiguous
Zhaohui Cui et al.
Langmuir : the ACS journal of surfaces and colloids, 26(1), 179-182 (2009-08-04)
The in situ crystallization technique has been utilized to fabricate zirconium phenylphosphonate (ZrPP) films with their hexagonal crystallite perpendicular to the copper substrate. The micro/nano roughness surface structure, as well as the intrinsic hydrophobic characteristic of the surface functional groups
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  1. How can I determine the shelf life / expiration / retest date of this product?

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    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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