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重要文件

M29908

Sigma-Aldrich

苯甲酸甲酯

99%

同義詞:

苯甲酸甲酯

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About This Item

線性公式:
C6H5COOCH3
CAS號碼:
分子量::
136.15
Beilstein:
1072099
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22
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蒸汽密度

4.68 (vs air)

品質等級

蒸汽壓力

<1 mmHg ( 20 °C)

化驗

99%

形狀

liquid

折射率

n20/D 1.516 (lit.)

bp

198-199 °C (lit.)

mp

−12 °C (lit.)

溶解度

H2O: soluble 2.1 g/L at 20 °C

密度

1.088 g/mL at 20 °C (lit.)

SMILES 字串

COC(=O)c1ccccc1

InChI

1S/C8H8O2/c1-10-8(9)7-5-3-2-4-6-7/h2-6H,1H3

InChI 密鑰

QPJVMBTYPHYUOC-UHFFFAOYSA-N

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一般說明

苯甲酸甲酯是一种挥发性芳香族酯化合物,广泛用于香料工业。[1][2]这种成分在番石榴、芒果和奇异果中天然存在。

應用

苯甲酸甲酯(C6H5CO2CH3)可用作以下反应的前体:
  • 使用载体锰氧化物催化剂选择性合成苯甲醛。[3][4];
  • 通过傅-克酰基化与芳基化合物反应制备二苯甲酮衍生物。[5]

象形圖

Health hazardExclamation mark

訊號詞

Warning

危險聲明

危險分類

Acute Tox. 4 Oral - Repr. 2

儲存類別代碼

10 - Combustible liquids

水污染物質分類(WGK)

WGK 1

閃點(°F)

170.6 °F - Pensky-Martens closed cup

閃點(°C)

77 °C - Pensky-Martens closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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分析證明 (COA)

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存取文件庫

Characterization and Activity of MnO/γ-Al2O3 for Hydrogenation of Methyl Benzoate to Benzaldehyde
Xu H-L, et al.
Chin. J. Chem., 19(7), 647-651 (2001)
Direct aerobic oxidation of primary alcohols to methyl esters catalyzed by a heterogeneous gold catalyst
Nielsen IS, et al.
Catalysis Letters, 116(1-2), 35-40 (2007)
Hydrogenation of methyl benzoate to benzaldehyde over manganese oxide catalysts prepared from Mg/Mn/Al hydrotalcite-like compounds
Chen A, et al.
Applied Catalysis A: General, 274(1-2), 101-109 (2004)
N Dudareva et al.
The Plant cell, 12(6), 949-961 (2000-06-15)
In snapdragon flowers, the volatile ester methyl benzoate is the most abundant scent compound. It is synthesized by and emitted from only the upper and lower lobes of petals, where pollinators (bumblebees) come in contact with the flower. Emission of
Md Munir Mostafiz et al.
Insects, 11(6) (2020-06-24)
Benzoates (naturally occurring plant toxins) produce pesticidal effects on various pest insects and mites, but their effects on non-target insects are poorly understood. In this study, we evaluate the lethal and sublethal toxicity of methyl benzoate (MB) to adults of

Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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